金湖凹陷西斜坡油气运移分子地球化学研究

李素梅; 曾凡刚; 庞雄奇; 金之钧; 黎茂稳; 许正龙

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金湖凹陷西斜坡油气运移分子地球化学研究

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙

文章导航 > 沉积学报 > 2001 > 19(3): 459-464

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

引用本文:

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

LI Su mei, ZENG Fan gang, PANG Xiong qi, JIN Zhi jun, LI Mao wen, XU Zheng long. Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China[J]. Acta Sedimentologica Sinica, 2001, 19(3): 459-464.

Citation:

LI Su mei, ZENG Fan gang, PANG Xiong qi, JIN Zhi jun, LI Mao wen, XU Zheng long. Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China[J]. Acta Sedimentologica Sinica, 2001, 19(3): 459-464.

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

引用本文:

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

Citation:

金湖凹陷西斜坡油气运移分子地球化学研究

1.
石油大学北京昌平 102200;
2.
加拿大联邦地质词查局 Canada;
3.
中国人民大学环境学院北京 100872;
4.
江苏石油勘探局江苏扬州 225000

基金项目: 国家重点基础研究项目(G1999—43310)资助

详细信息

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

中图分类号: P618.13

计量

文章访问数: 735
HTML全文浏览量: 27
PDF下载量: 475
被引次数: 0

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

1.
Petroleum University,Beijing 102200;
2.
Geology Survey of Canada,Calgary Canada;
3.
School of Environment and Resource,Renming University of chian 100872;
4.
Jiangsu Petroleum Exploration Bureau,Yangzhou Jiangsu 225000

摘要

摘要: 应用非烃技术、多馏分绝对定量技术,在分析苏北金湖凹陷原油、烃源岩地球化学特征、油源对比的基础上,重点对吡咯类含氮化合物在岩—油、油—油运移中的分馏效应进行了研究,并对骨架相似的另两类杂原子化合物—氧芴 (二苯并呋喃 )、硫芴 (二苯并噻吩 )的运移分馏效应作了初步探讨。结果表明,金湖凹陷西斜坡原油中吡咯类化合物具有较好的运移分馏效应,油气主体运移方向为东北至西南,相邻的三河次凹为其主要的油源区;杂原子化合物—氧芴、硫芴系列运移分馏效应不及吡咯类;绝对定量技术可弥补常规生物标志物在油气二次运移过程中异构体间分馏效应难以观察的不足,可作为继非烃技术后的另一评价油气运移过程的重要工具。
- 吡咯类化合物 /
- 氧芴 /
- 硫芴 /
- 芴 /
- 芳烃 /
- 绝对定量 /
- 分馏效应
Abstract: Oil migration effect of the western slope, Jinhu Depression of Subei Basin, Eastern China is observed on the base of detailed work of investigating genetic mechanism and source rock of the petroleum. The methods of the study adopted include non hydrocarbon and absolute quantitative analysis of biomarkers and the other kind of the compounds in different fractions by co injection of standard compounds. The main method is emphasized on studying the migration fractionation effect of pyrrolic nitrogen compounds in the oil. The other two kind compounds' migration fractionation effect is also observed, which are dibenzofuran and dibenzothiophene series with the similar molecular structure as the pyrrolic nitrogen compounds. The result indicates that the pyrrolic nitrogen compound in the oil has apparent migration fractionation effects, which infer the oil migration direction of the area is form northeast to southwest, and the Shanghe Sag is the main source cooker of the oil. The migration fractionation effects could also be observed in the other two kind compound series dibenzofuran and dibenzothiophene bearing oxygen and sulfur heteroatom respectively, which make the compounds having strong polarity too. However, their fractionation effects are not apparent as the nitrogenic compound. The migration fractionation effects of the three compounds increase according to the order of dibenzoghiophene, dibenzofuran and nitrogen compounds, which infer the polarity of the three kind compounds increasing according to the order. It is probably the hetroatoms in the compounds determining the chemical characteristics of the compounds. The results also indicate that the absolute quantitative analysis is very useful in study petroleum migration, the migration fractionation effect could be observed from the abundance variation of some high molecular compounds, especially the heterocyclic compounds such as NSO' compounds metioned above.
- pyrrolic /
- nitrogen /
- compounds /
- dibenzofuran /
- dibenzothiophene /
- absolute quantitative analysLs /
- migration effect．

HTML全文

参考文献(1)

[1]

1.彼得斯KE;莫尔多万J M;姜乃煌生物标记化合物指南-古代沉积物和石油中分子化石的解释.!!北京:石油工业出版社 1995

2.李素梅;刘洛夫;王铁冠吡咯类化合物与生物标志物油气运移效果对比研究[期刊论文]-石油勘探与开发2000(04)

3.Dorbon M;Schmitter J M;Garrigues P Distribution of carbazole derivatives in petroleum[外文期刊]1984

4.LiM;Larter S R;Stoddart D Fractionation of pyrrolic nitrogen compounds in petroleum during migration-Derivation of migration related geochemical parameters

5.李素梅;张爱云;王铁冠朝长地区原油中的有机氮化合物及应用[期刊论文]-现代地质 1999(04)

6.刘洛夫;毛东风石油运移研究的新方法[期刊论文]-地球科学进展 1996(06)

7.王铁冠;李素梅;张爱云应用含氮化合物探讨新疆轮南油田油气运移[期刊论文]-地质学报 2000(01)

8.LiM;LarterSR;StoddartD Pracfcal liquid chromatographic separation schemes for pyrrolic andpyridinic nitrogen aromatic hetero-cycle fractions from crude oils suitable for rapid characterisation of geo-chernical samples

9.李索梅;王铁冠;张爱云原油中吡咯类化合物的分布特征及其地球化学意义[期刊论文]-沉积学报 1999(02)

10.李素梅;庞雄奇沉积物中氮硫氧杂环芳烃的分布特征及其地球化学意义

11.刑其毅;徐瑞秋;周政基础有机化学 1994

12.England;Mann DM The movement and enstraprnent of petroleurm fluids in the subsurface 1987

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文章访问数: 735
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金湖凹陷西斜坡油气运移分子地球化学研究

1. 石油大学北京昌平 102200;

2. 加拿大联邦地质词查局 Canada;

3. 中国人民大学环境学院北京 100872;

4. 江苏石油勘探局江苏扬州 225000

基金项目: 国家重点基础研究项目(G1999—43310)资助

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

收稿日期: 2000-07-27
修回日期: 2001-01-02
刊出日期: 2001-09-10

中图分类号: P618.13

关键词:

吡咯类化合物 /

氧芴 /

硫芴 /

芴 /

芳烃 /

绝对定量 /

分馏效应

摘要: 应用非烃技术、多馏分绝对定量技术,在分析苏北金湖凹陷原油、烃源岩地球化学特征、油源对比的基础上,重点对吡咯类含氮化合物在岩—油、油—油运移中的分馏效应进行了研究,并对骨架相似的另两类杂原子化合物—氧芴 (二苯并呋喃 )、硫芴 (二苯并噻吩 )的运移分馏效应作了初步探讨。结果表明,金湖凹陷西斜坡原油中吡咯类化合物具有较好的运移分馏效应,油气主体运移方向为东北至西南,相邻的三河次凹为其主要的油源区;杂原子化合物—氧芴、硫芴系列运移分馏效应不及吡咯类;绝对定量技术可弥补常规生物标志物在油气二次运移过程中异构体间分馏效应难以观察的不足,可作为继非烃技术后的另一评价油气运移过程的重要工具。

English Abstract

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

1. Petroleum University,Beijing 102200;

2. Geology Survey of Canada,Calgary Canada;

3. School of Environment and Resource,Renming University of chian 100872;

4. Jiangsu Petroleum Exploration Bureau,Yangzhou Jiangsu 225000

Received Date: 2000-07-27
Rev Recd Date: 2001-01-02
Publish Date: 2001-09-10

Keywords:

Abstract: Oil migration effect of the western slope, Jinhu Depression of Subei Basin, Eastern China is observed on the base of detailed work of investigating genetic mechanism and source rock of the petroleum. The methods of the study adopted include non hydrocarbon and absolute quantitative analysis of biomarkers and the other kind of the compounds in different fractions by co injection of standard compounds. The main method is emphasized on studying the migration fractionation effect of pyrrolic nitrogen compounds in the oil. The other two kind compounds' migration fractionation effect is also observed, which are dibenzofuran and dibenzothiophene series with the similar molecular structure as the pyrrolic nitrogen compounds. The result indicates that the pyrrolic nitrogen compound in the oil has apparent migration fractionation effects, which infer the oil migration direction of the area is form northeast to southwest, and the Shanghe Sag is the main source cooker of the oil. The migration fractionation effects could also be observed in the other two kind compound series dibenzofuran and dibenzothiophene bearing oxygen and sulfur heteroatom respectively, which make the compounds having strong polarity too. However, their fractionation effects are not apparent as the nitrogenic compound. The migration fractionation effects of the three compounds increase according to the order of dibenzoghiophene, dibenzofuran and nitrogen compounds, which infer the polarity of the three kind compounds increasing according to the order. It is probably the hetroatoms in the compounds determining the chemical characteristics of the compounds. The results also indicate that the absolute quantitative analysis is very useful in study petroleum migration, the migration fractionation effect could be observed from the abundance variation of some high molecular compounds, especially the heterocyclic compounds such as NSO' compounds metioned above.

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

引用本文:

李素梅, 曾凡刚, 庞雄奇, 金之钧, 黎茂稳, 许正龙. 金湖凹陷西斜坡油气运移分子地球化学研究[J]. 沉积学报, 2001, 19(3): 459-464.

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金湖凹陷西斜坡油气运移分子地球化学研究

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

计量

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

计量

目录

金湖凹陷西斜坡油气运移分子地球化学研究

1. 石油大学北京昌平 102200;

2. 加拿大联邦地质词查局 Canada;

3. 中国人民大学环境学院北京 100872;

4. 江苏石油勘探局江苏扬州 225000

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

English Abstract

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

1. Petroleum University,Beijing 102200;

2. Geology Survey of Canada,Calgary Canada;

3. School of Environment and Resource,Renming University of chian 100872;

4. Jiangsu Petroleum Exploration Bureau,Yangzhou Jiangsu 225000

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金湖凹陷西斜坡油气运移分子地球化学研究

作者简介: 李素梅,女,1968年出生,博士后,有机地球化学

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出版历程

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

计量

出版历程

目录

金湖凹陷西斜坡油气运移分子地球化学研究

1. 石油大学北京昌平 102200; 2. 加拿大联邦地质词查局 Canada; 3. 中国人民大学环境学院北京 100872; 4. 江苏石油勘探局江苏扬州 225000

作者简介: 李素梅,女,1968年出生,博士后,有机地球化学

English Abstract

Oil Migration Study of the Western Slope,Jinhu Depressionof Subei Basin,Eastern China

1. Petroleum University,Beijing 102200; 2. Geology Survey of Canada,Calgary Canada; 3. School of Environment and Resource,Renming University of chian 100872; 4. Jiangsu Petroleum Exploration Bureau,Yangzhou Jiangsu 225000

全文HTML

目录

友情链接

期刊在线

联系我们

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

1. 石油大学北京昌平 102200;

2. 加拿大联邦地质词查局 Canada;

3. 中国人民大学环境学院北京 100872;

4. 江苏石油勘探局江苏扬州 225000

作者简介:
李素梅,女,1968年出生,博士后,有机地球化学

1. Petroleum University,Beijing 102200;

2. Geology Survey of Canada,Calgary Canada;

3. School of Environment and Resource,Renming University of chian 100872;

4. Jiangsu Petroleum Exploration Bureau,Yangzhou Jiangsu 225000