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Lu Jialan, Zhuang Hanging, Liu Wenjun. The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit[J]. Acta Sedimentologica Sinica, 1997, 15(2): 226-231.
Citation: Lu Jialan, Zhuang Hanging, Liu Wenjun. The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit[J]. Acta Sedimentologica Sinica, 1997, 15(2): 226-231.

The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit

  • Received Date: 1996-06-12
  • Publish Date: 1997-04-10
  • The role of organic matter in the formation of strata-bound Pb-Zn deposits was discussed widely.The experimental studies in this paper included three aspects as follow:1. The partition coefficients of Pb2+ and Zn2+between、oexisting liquid oil and aqueous phase weredetermined in aqueous solutions with various pH and composition. The results suggested that Cu, Pb, andZn ahow a strong tendency to enrich liquid oil in alkaline aqueous solution, and that in acid conditionthese elements were still enriched in aqueous solution phase. 2. The solubilities of sphalerite and galena in oilfield brine and CaCl2-NaCl solution, which had thesame salinities as the brine, were determined, respectively. Furthermore, the competitive abilities of metalelements betty een o rgani c a nd ino rganic com posi do ns in oilfi eld brine w ere di scus sed. 3. Based on the hypothesis of double source rocks, the relationship between formation and primarymigration of oil and mobilization of lead and zinc were studies experimentally. The results showed thatth e concentration of Zn in chloroform extractsmetal elements were obtained in migrated oil asup to 52一691u-g/g and that higher concentrations ofTherefore, it was reasonably suggested that liquid oil is an important carrier of metal elements andimportant composition of ore-forming fluid at appropriate maturity limit of oil evolution.
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    2 涂光炽等著.中国层控.床地球化学(第三卷).北京:科学出版社.1988.27-36

    3 傅家漠.彭平安.林清等t层控矿床有机地球化学研究的儿个问题.中国科学院地球化学研究所有机地球化学开放实验室年报(1988).北京:科学出版社.1990.174-185.

    4 Marikos M A, Landon R C and Leventhal ,J S. Solid insoublebitumen in the Magmont Westorebody, southeast Missouri. 1rcon Geo1.1986.81 1933-1998

    5 Gize P G and Barnes H L. The oranic geochenistryMississippi Valley-type lead-zinc deposits. Lcon Geoh 1987, 82 457-470.

    6 尹汉辉等著.滇西地注构造与成矿.长沙:中南工业人学出版社,1993, 86-91

    7 Montacer M, Disrwar ,J R.Orgeval ,J ,J, and Trichet ,J. Relation-ship between Zn-Pb ore and oil accumllation processes Exam-ple of the Bou Grine deposit(Tunisia). Advances in Organicochemistry 1987, Org. Geochem.13(1-3): 423-431.

    8 陈庆年.贾蓉芬刘德汉.丹寨汞金矿床有机质与金属的某些特征.中国科学院地球化学研究所有机地球化学开放实验室年报(1986).贵阳:贵州人民出版社.1986.145-158

    9 Lu Jialan.l}u Jiamo. Liu Jinzhong and Ghang Huizhit The rela-tionship between oil generation/primary migration and metalmineralization. Poster Sessions from the 16th htermationalMeeting on Organic Geochemistry, Stavanger, 1993, 615-617.

    10 Manning D A C and Gize P G 'fhe role of organic matter inore transport processes. iri Organic Geochemistry(ed. by M HL,ngel and S A Macko). Plenum Press, New York, 1993, 547-563

    11 卢家烂.金属成矿理论的新认识.全国第四届矿物岩石地球化学学术讨论会论文摘要编.北京:地震出版社.1991. 76.

    12 卢家烂.煤成烃的模拟实验.傅家漠等主编《煤成烃地球化学》.北京:科学出版社.1990.37-48.

    14 Sverjensky D A. Oil field brines as ore-orming solutions. 1rcon Geol, 1984, 79 23-37.

    14 Giralano 'f Hand Drummond S E. The potentiometric deter urination of stability constants for zinc acetate complexes in aqueous solutions to 295℃ Geochim Cosmochim Acta. 1991. 55 2401-2415.

    15 刘德汉林茂福.碳沥青中)种钒、镍矿物的发现和成因讨论. 中国科学(B辑).1983, (10): 935-939.
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  • Received:  1996-06-12
  • Published:  1997-04-10

The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit

Abstract: The role of organic matter in the formation of strata-bound Pb-Zn deposits was discussed widely.The experimental studies in this paper included three aspects as follow:1. The partition coefficients of Pb2+ and Zn2+between、oexisting liquid oil and aqueous phase weredetermined in aqueous solutions with various pH and composition. The results suggested that Cu, Pb, andZn ahow a strong tendency to enrich liquid oil in alkaline aqueous solution, and that in acid conditionthese elements were still enriched in aqueous solution phase. 2. The solubilities of sphalerite and galena in oilfield brine and CaCl2-NaCl solution, which had thesame salinities as the brine, were determined, respectively. Furthermore, the competitive abilities of metalelements betty een o rgani c a nd ino rganic com posi do ns in oilfi eld brine w ere di scus sed. 3. Based on the hypothesis of double source rocks, the relationship between formation and primarymigration of oil and mobilization of lead and zinc were studies experimentally. The results showed thatth e concentration of Zn in chloroform extractsmetal elements were obtained in migrated oil asup to 52一691u-g/g and that higher concentrations ofTherefore, it was reasonably suggested that liquid oil is an important carrier of metal elements andimportant composition of ore-forming fluid at appropriate maturity limit of oil evolution.

Lu Jialan, Zhuang Hanging, Liu Wenjun. The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit[J]. Acta Sedimentologica Sinica, 1997, 15(2): 226-231.
Citation: Lu Jialan, Zhuang Hanging, Liu Wenjun. The Experimental Studies on the Role of Organic Matter in Formation of Strata-bound Pb-Zn Deposit[J]. Acta Sedimentologica Sinica, 1997, 15(2): 226-231.
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