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Article Navigation >  Acta Sedimentologica Sinica  > 2005  >  23(1): 183-186

ZHANG Zai-long, REN Yong-hong, ZHANG Tong-yao, LI Xue-li. The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature[J]. Acta Sedimentologica Sinica, 2005, 23(1): 183-186.
Citation: ZHANG Zai-long, REN Yong-hong, ZHANG Tong-yao, LI Xue-li. The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature[J]. Acta Sedimentologica Sinica, 2005, 23(1): 183-186.
shu

The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature

  • College of Chemistry & Chemical Engineering, University of Petroleum, Dongying Shandong 257061

  • Received Date: 2004-04-04
  • Rev Recd Date: 2004-09-09
  • Publish Date: 2005-03-10
  • The evaluation of pressure effects is obtained by performing the hydrolysis of methyl octadecanonate as a model reaction catalyzed by seven different samp les of immature source rock that had first been extracted with organic solvents. The results show that p ressure plays an important role in the reaction and the pressure effects are not negligible. The pressure effects are different among the seven immature source rock. As a conquence, an enhanced or lowered ratios of hydrolysis takes place as a result of the pressure effects. The reasons that lead to such a result are discussed. It is suggested that the pressure effects observed is a complex of the promotion and restraint caused by pressure.
  • [1] 1 解启来,范善发,周中毅. 压力对烃源层演化及产烃影响的模拟实验[J].矿物岩石地球化学通报,1996,(02):91-93.

    2 陈晓东,王先彬. 压力对有机质成熟和油气生成的影响[J].地球科学进展,1999,(01):31-36.

    3 PriceLC,Wenger L M. The influence of pressure on petroleum generation and maturation as suggested by aqueous pyrolysis[J].Organic Geochemistry,1992,(02):141-159.

    4 史继扬,向明菊,屈定创. 氨基酸、脂肪酸对过渡带气、低熟原油形成的意义[J].沉积学报,1995,(02):84-88.

    5 王铁冠,钟宁宁. 低熟油气形成机理与分布[M].北京:石油工业出版社,1995.

    6 张在龙,劳永新,王培建. 盐水对未熟生油岩中脂肪酸催化脱羧生烃的影响[J].石油大学学报(自然科学版),2000,(06):57-60.

    7 张在龙,王广利,劳永新. 未熟烃源岩中矿物低温催化脂肪酸脱羧生烃动力学模拟实验研究[J].地球化学,2000,(04):322-326.

    8 张在龙,卢国林,刘洪祥. 用射频低温氧化法去除未熟烃源岩中的有机质方法研究[J].石油大学学报(自然科学版),2003,(04):110-112.

    9 邓宏文,钱凯. 沉积地球化学与环境分析[M].兰州:甘肃科学技术出版社,1993.96-97.

    10 傅献彩,沈文霞,姚天扬. 物理化学[M].北京:高等教育出版社,1990.742-743.

    11 DomineF,Enguehatd F. Kinetics of heane pyrolysis at very high pressure-3,Application to geochemical modeling[J].Organic Geochemistry,1992,(01):41-49.

    12 EnguehardF,Kressmann S,Domine F. Kientics of dibuty lether pyrosis at high pressure: Experimental study[J].Organic Geochemistry,1990,(1-3):155-160.

    13 DomineF. High pressure pyrolysis of n-hexane,2,4-dimethypentane and 1-phenylbutane Is pressure an important geochemical parameter[J].Organic Geochemistry,1991,(05):619-634.
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  • Received:  2004-04-04
  • Revised:  2004-09-09
  • Published:  2005-03-10

The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature

  • College of Chemistry & Chemical Engineering, University of Petroleum, Dongying Shandong 257061
  • Received Date: 2004-04-04
  • Rev Recd Date: 2004-09-09
  • Publish Date: 2005-03-10

Abstract: The evaluation of pressure effects is obtained by performing the hydrolysis of methyl octadecanonate as a model reaction catalyzed by seven different samp les of immature source rock that had first been extracted with organic solvents. The results show that p ressure plays an important role in the reaction and the pressure effects are not negligible. The pressure effects are different among the seven immature source rock. As a conquence, an enhanced or lowered ratios of hydrolysis takes place as a result of the pressure effects. The reasons that lead to such a result are discussed. It is suggested that the pressure effects observed is a complex of the promotion and restraint caused by pressure.

ZHANG Zai-long, REN Yong-hong, ZHANG Tong-yao, LI Xue-li. The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature[J]. Acta Sedimentologica Sinica, 2005, 23(1): 183-186.
Citation: ZHANG Zai-long, REN Yong-hong, ZHANG Tong-yao, LI Xue-li. The Influence of Pressure on Hydrolysis of Fatty Ac id Esters Catalysed by Immature Source Rock at Low Temperature[J]. Acta Sedimentologica Sinica, 2005, 23(1): 183-186.
shu

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