Application of Strontium Isotope Stratigraphy to Diagenesis Research

HUANG Si-jing; SHI He; ZHANG Meng; SHEN Li-cheng; WU Wen-hui

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Article Navigation > Acta Sedimentologica Sinica > 2002 > 20(3): 359-366

HUANG Si-jing, SHI He, ZHANG Meng, SHEN Li-cheng, WU Wen-hui. Application of Strontium Isotope Stratigraphy to Diagenesis Research[J]. Acta Sedimentologica Sinica, 2002, 20(3): 359-366.

Citation:

HUANG Si-jing, SHI He, ZHANG Meng, SHEN Li-cheng, WU Wen-hui. Application of Strontium Isotope Stratigraphy to Diagenesis Research[J]. Acta Sedimentologica Sinica, 2002, 20(3): 359-366.

Application of Strontium Isotope Stratigraphy to Diagenesis Research

State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation,Chengdu University of Technology, Chengdu,610059

Received Date: 2001-12-17
Rev Recd Date: 2002-05-17
Publish Date: 2002-09-10

Abstract

Based on the fundamental principle of StrontiumIsotope Strati graphy(SIS），i.e. strontium isotope composition of seawater is a determined value during the same geological time,we can apply the SISto the research of clastic diagenesis in order to esti matethe effect of marine f acies and non- mari ne facies on diagenesis. three eXamples for t he application from Ahujiangkou Basin,Southern China Sea,ordos Basin,and Bohai wan Basi nare shown as follows ：(1)the composition of stronti umisotope of marine clastic diagenesisfluid developed in a regular pathway.Because of the dissolution of feldspar and other terri genous silicate minerals in diagenesis，the ratio of ⁸⁷Sr/⁸⁶Sr of later carbonate cements in diagenesis are usually higher than that of earlier one，and the ori ginal value of the evolution process is the ratio of ⁸⁷Sr/⁸⁶Sr of sea water in the same term，which is a determined value.(2)the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement in terrestrial sandstones may be lower than that of continental meteoric water when the strontiumfromt he mantle influenced the syngenesis water,or the marine facies influenced the diagenesis water by dissolution of older terri genous carbonate rock fragments. However,the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement preci pitated during later burial diagenesis is also higher than that precipitated during earlier period.(3)When the fluid fromthe mantle controlled the full diagenesis process,and if the inference from mantle strontiumis strong enough to erase or to decrease the difference of strontium isotope composition of various carbonate cements caused by the terrestrial effect in different diagenesis period or different diagenesis degrees，the ratio of⁸⁷Sr/⁸⁶Sr of carbonate cements precipitated in different diagenesis periods are all very low and，theref ore，it is lack of the evolution pattern,which often appears in other sedimentary basin,and the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement precipitated during later burial diagenesis is higher than that precipitated during earlier period.

References

[1]	Wickman F E. Isotope ratios: a clue to the age of certain marine sediments[J]. Journal of Geology, 1948,56:61～66
[2]	McArthur J M, Burnett J, Hancock J M. Strontium isotopes at K/ T boundary; discussion[J]. Nature (London), 1992,355(6355):28
[3]	Graustein W C. Stable isotopes in ecological research[M].New York: Springer, 1989.491～512
[4]	McArthur J M. Recent trends in strontium isotope stratigraphy[J]. Terra Nova,1994, 6:331～358
[5]	黄思静,石和,刘洁,沈立成. 锶同位素地层学研究进展[J]. 地球科学进展,2001,16(2):194～200[Huang Sijing,Shi He,Liu Jie,Shen Licheng. Progress in Strontium Isotope Stratigraphy[J]. Advance in Earth Sciences, 2001,16(2): 194～200 (in Chinese with English abstract)]
[6]	Hess J, Stott L D, Bender M L K, Kennet J P and Schilling J G. The Oligocene marine microfossil record: age assessments using strontium isotopes[J]. Paleoceanography, 1989,4:655～679
[7]	Miller K G, Feigenson M D, Wright J D, et al. Miocene isotope reference section, Deep Sea Drilling Project Site 608: an evaluation of isotope and biostratigraphic resolution[J]. Paleoceanography, 1991, 6:33～52
[8]	McArthur J M, Kennedy W J, Chen M, Thirlwall M F and Gale A S. Strontium isotope stratigraphy for the Late Creataceous: direct numerical age calibration of the Sr-isotope curve for the U.S. Western interior Seaway. Palaeogeogr. Palaeoclim[J]. Palaeoecol, 1994,108:95～119
[9]	Howarth R J, McArthur J M. Statistics for strontium isotope stratigraphy: a robust LOWESS fit to marine Sr-isotope curve for 0 to 206 Ma, with look-up table for derivation of numeric age[J]. J. Geol.,1997,105: 441～456
[10]	Oslick J S, Miller K G, Feigenson M D,Clement B M. Oligocene-Miocene Sr isotopes; correlations to an inferred glacioeustatic record[J]. Eos, Transactions, American Geophysical Union, 75(16, Suppl):202
[11]	Crame J A, McArthur J M, Pirrie D, Riding J B. Strontium isotope correlation of the basal Maastrichtian Stage in Antarctica to the Ruropean and US biostratigrapic scheme[J]. Jorunal of the Geological Society, London, 1999,156:957～964
[12]	黄思静.川西北甘溪中、上泥盆统海相碳酸盐岩的碳、锶同位素组成及其地质意义[J]. 岩石学报, 1993,9(增刊): 214～221[Huang Sijing. Carbon and strontium isotopes of marine carbonate rocks of Middle-upper Devonian in Ganxi, northwestern Sichuan province and their geological significance[J]. Acta Petrologica Sinica,1993, 9(Suppl.):214～221 (in Chinese with English abstract)]
[13]	黄思静.上扬子地台区晚古生代海相碳酸盐岩的碳、锶同位素研究[J]. 地质学报, 1997,71(1):45～53[Huang Sijing. Carbon and strontium isotopes of Late Palaeozoic marine carbonates in the Upper Yangtze platform, southwest China[J].Acta Geologica Sinica,1997, 71(1):45～53 (in Chinese with English abstract)]
[14]	陈骏,仇纲,杨杰东.黄土碳酸盐Sr同位素组成与原生和次生碳酸盐识别[J]. 自然科学进展, 1997,7(6): 731～734[Chen Jun, Qiu Gang, Yang Jiedong. Strontium isotope composition in carbonates of loess and the identification of original and secondary carbonate[J]. Progress in Natural Science, 1997,7(6):731～734 (in Chinese with English abstract)]
[15]	刘传联, 成鑫荣. 渤海湾盆地早第三纪非海相钙质超微化石的锶同位素证据[J]. 科学通报,1996,41(10): 908～910[Liu Chuanlia, Cheng Xinrong.Strontium isotope evidence of nonmarine calcic micro-fossil in the Early Tertiary in the Behai Basin[J]. Chinese Science Bulletin,1996, 41(10):908～910 ]
[16]	王世杰,董丽敏,林文祝,李春来,汪品先,赵泉鸿,吴锡浩. 泥河湾组有孔虫化石群的锶同位素研究[J].科学通报, 1995,40(22): 2 072～2 074[Wang Shijie, Dong Limin, Lin Wenzhu, Li Chunlai, Wang Pinxian, Zhao Quanhon, Wu Xihao. Study of strontium isotope of the Foraminifer fossil Group in the Nihewan Formation[J]. Chinese Science Bulletin, 1995,40(22): 2 072～2 074]
[17]	Lynch F L and Land L S. Diagenesis of calcite cement in Frio formation sandstones and its relationship to formation water chemistry[J]. Journal of Sedimentary Research, 1996,66(3): 439～446
[18]	Taylor K G, Gawthorpej R L, Curtis C D, Marshall J D, Awwiller D N. Carbonate cementation in a sequence-stratigraphic framework: Upper Cretaceous sandstones, Book Cliffs, Utah-Colorado[J]. Journal of sedimentary research, 2000,70(2):360～372
[19]	Kantorowicz J D, Bryant I D, and Dawans J M. Controls on the geometry and distribution of carbonate cements in Jurassic sandstones: Bridport Sands, southern England and Viking Group,Troll Field, Norway[A]. In: Marshall J D, ed. Diagenesis of Sedimentary Sequences: Geological Society of London, Special Publication,1987,36: 103～118
[20]	徐北煤, 卢冰. 硅质碎屑岩中碳酸盐胶结物及其对储层的控制作用的研究[J]. 沉积学报, 1994, 12(3): 56～66[Xu Beimei, Lu Bing, The study of diagenetic carbonate in siliciclastic rock and its control in the reservoir[J].Acta Sedimentologica Sinica, 1994,6(4): 56～66]
[21]	McArthur J M, Howarth R J, Bailey T R. Strontium Isotope Stratigraphy: LOWESS Version 3: Best Fit to the Marine Sr-Isotope Curve for 0～509 Ma and Accompanying Look-up Table for Deriving Numerical Age[J]. J. Geol., 2001,109:155～170
[22]	Veizer J, Ala D, Azmy K, Bruckschen P, Buhl D, Bruhn F, Garden G A F,et al. 87 Sr/ 86 Sr, δ¹³C and δ^18O evolution of Phanerozoic seawater[J]. Chem. Geol., 1999,161:59～88
[23]	Palmer M R, Edmond J M. The strontium isotopic budget of the modern ocean[J]. Earth Planet.Sci. Lett., 1994,92:11～26
[24]	Veizer J, Fritz P,Jones B. Geochemistry of brachiopods: Oxygen and carbon isotope records of Paleozoic oceans[J]. Geochim. Cosmochim. Acta. 1986, 50: 1 679～1 696
[25]	黄思静. 海相碳酸盐矿物的阴极发光性与其成岩蚀变的关系[J]. 岩相古地理, 1990, 4: 9～15[Huang Sijing.Cathodoluminescence and diagenetic alteration of marine carbonate minerals[J]. Sedimentary Facies and Palaeogeography,1990.(4): 9～15]
[26]	Palmer A R,Geissman J. Geologic time scale. The Geological Society of America, Product code CTS004,1999
[27]	朱国华. 陕北延长组成岩圈闭油藏的形成及其重要意义[J]. 沉积学报, 1988,6(4): 1～11[Zhu Guohua. Formation of diagenetic trapping reservoir of Yan Chang Formation, in Northern Shaanxi and its Significance[J]. Acta Sedimentologica Sinica,1988, 6(4): 1～11]
[28]	Qing H, Barnes C R, Buhl D and Veizer J. The strontium isotopic composition of Ordovician and Silurian brachiopods and conodonts: Relationships to geological events and implications for coeval seawater[J]. Geochim. Cosmochim. Acta, 1998,62(10): 1 721～1 733

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沈阳化工大学材料科学与工程学院沈阳 110142

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Application of Strontium Isotope Stratigraphy to Diagenesis Research

State Key Laboratory of Oil/Gas Reservoir Geology and Exploitation,Chengdu University of Technology, Chengdu,610059

Received Date: 2001-12-17

Rev Recd Date: 2002-05-17

Publish Date: 2002-09-10

Key words:

strontium isotope stratigraphy /
influence of marine and non- marine facies /
clastic diagenesis /
evolution pathway of strontium isotope for diagenetic fluids

Abstract: Based on the fundamental principle of StrontiumIsotope Strati graphy(SIS），i.e. strontium isotope composition of seawater is a determined value during the same geological time,we can apply the SISto the research of clastic diagenesis in order to esti matethe effect of marine f acies and non- mari ne facies on diagenesis. three eXamples for t he application from Ahujiangkou Basin,Southern China Sea,ordos Basin,and Bohai wan Basi nare shown as follows ：(1)the composition of stronti umisotope of marine clastic diagenesisfluid developed in a regular pathway.Because of the dissolution of feldspar and other terri genous silicate minerals in diagenesis，the ratio of ⁸⁷Sr/⁸⁶Sr of later carbonate cements in diagenesis are usually higher than that of earlier one，and the ori ginal value of the evolution process is the ratio of ⁸⁷Sr/⁸⁶Sr of sea water in the same term，which is a determined value.(2)the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement in terrestrial sandstones may be lower than that of continental meteoric water when the strontiumfromt he mantle influenced the syngenesis water,or the marine facies influenced the diagenesis water by dissolution of older terri genous carbonate rock fragments. However,the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement preci pitated during later burial diagenesis is also higher than that precipitated during earlier period.(3)When the fluid fromthe mantle controlled the full diagenesis process,and if the inference from mantle strontiumis strong enough to erase or to decrease the difference of strontium isotope composition of various carbonate cements caused by the terrestrial effect in different diagenesis period or different diagenesis degrees，the ratio of⁸⁷Sr/⁸⁶Sr of carbonate cements precipitated in different diagenesis periods are all very low and，theref ore，it is lack of the evolution pattern,which often appears in other sedimentary basin,and the ratio of ⁸⁷Sr/⁸⁶Sr of carbonate cement precipitated during later burial diagenesis is higher than that precipitated during earlier period.

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Reference (28)

[1]	Wickman F E. Isotope ratios: a clue to the age of certain marine sediments[J]. Journal of Geology, 1948,56:61～66
[2]	McArthur J M, Burnett J, Hancock J M. Strontium isotopes at K/ T boundary; discussion[J]. Nature (London), 1992,355(6355):28
[3]	Graustein W C. Stable isotopes in ecological research[M].New York: Springer, 1989.491～512
[4]	McArthur J M. Recent trends in strontium isotope stratigraphy[J]. Terra Nova,1994, 6:331～358
[5]	黄思静,石和,刘洁,沈立成. 锶同位素地层学研究进展[J]. 地球科学进展,2001,16(2):194～200[Huang Sijing,Shi He,Liu Jie,Shen Licheng. Progress in Strontium Isotope Stratigraphy[J]. Advance in Earth Sciences, 2001,16(2): 194～200 (in Chinese with English abstract)]
[6]	Hess J, Stott L D, Bender M L K, Kennet J P and Schilling J G. The Oligocene marine microfossil record: age assessments using strontium isotopes[J]. Paleoceanography, 1989,4:655～679
[7]	Miller K G, Feigenson M D, Wright J D, et al. Miocene isotope reference section, Deep Sea Drilling Project Site 608: an evaluation of isotope and biostratigraphic resolution[J]. Paleoceanography, 1991, 6:33～52
[8]	McArthur J M, Kennedy W J, Chen M, Thirlwall M F and Gale A S. Strontium isotope stratigraphy for the Late Creataceous: direct numerical age calibration of the Sr-isotope curve for the U.S. Western interior Seaway. Palaeogeogr. Palaeoclim[J]. Palaeoecol, 1994,108:95～119
[9]	Howarth R J, McArthur J M. Statistics for strontium isotope stratigraphy: a robust LOWESS fit to marine Sr-isotope curve for 0 to 206 Ma, with look-up table for derivation of numeric age[J]. J. Geol.,1997,105: 441～456
[10]	Oslick J S, Miller K G, Feigenson M D,Clement B M. Oligocene-Miocene Sr isotopes; correlations to an inferred glacioeustatic record[J]. Eos, Transactions, American Geophysical Union, 75(16, Suppl):202
[11]	Crame J A, McArthur J M, Pirrie D, Riding J B. Strontium isotope correlation of the basal Maastrichtian Stage in Antarctica to the Ruropean and US biostratigrapic scheme[J]. Jorunal of the Geological Society, London, 1999,156:957～964
[12]	黄思静.川西北甘溪中、上泥盆统海相碳酸盐岩的碳、锶同位素组成及其地质意义[J]. 岩石学报, 1993,9(增刊): 214～221[Huang Sijing. Carbon and strontium isotopes of marine carbonate rocks of Middle-upper Devonian in Ganxi, northwestern Sichuan province and their geological significance[J]. Acta Petrologica Sinica,1993, 9(Suppl.):214～221 (in Chinese with English abstract)]
[13]	黄思静.上扬子地台区晚古生代海相碳酸盐岩的碳、锶同位素研究[J]. 地质学报, 1997,71(1):45～53[Huang Sijing. Carbon and strontium isotopes of Late Palaeozoic marine carbonates in the Upper Yangtze platform, southwest China[J].Acta Geologica Sinica,1997, 71(1):45～53 (in Chinese with English abstract)]
[14]	陈骏,仇纲,杨杰东.黄土碳酸盐Sr同位素组成与原生和次生碳酸盐识别[J]. 自然科学进展, 1997,7(6): 731～734[Chen Jun, Qiu Gang, Yang Jiedong. Strontium isotope composition in carbonates of loess and the identification of original and secondary carbonate[J]. Progress in Natural Science, 1997,7(6):731～734 (in Chinese with English abstract)]
[15]	刘传联, 成鑫荣. 渤海湾盆地早第三纪非海相钙质超微化石的锶同位素证据[J]. 科学通报,1996,41(10): 908～910[Liu Chuanlia, Cheng Xinrong.Strontium isotope evidence of nonmarine calcic micro-fossil in the Early Tertiary in the Behai Basin[J]. Chinese Science Bulletin,1996, 41(10):908～910 ]
[16]	王世杰,董丽敏,林文祝,李春来,汪品先,赵泉鸿,吴锡浩. 泥河湾组有孔虫化石群的锶同位素研究[J].科学通报, 1995,40(22): 2 072～2 074[Wang Shijie, Dong Limin, Lin Wenzhu, Li Chunlai, Wang Pinxian, Zhao Quanhon, Wu Xihao. Study of strontium isotope of the Foraminifer fossil Group in the Nihewan Formation[J]. Chinese Science Bulletin, 1995,40(22): 2 072～2 074]
[17]	Lynch F L and Land L S. Diagenesis of calcite cement in Frio formation sandstones and its relationship to formation water chemistry[J]. Journal of Sedimentary Research, 1996,66(3): 439～446
[18]	Taylor K G, Gawthorpej R L, Curtis C D, Marshall J D, Awwiller D N. Carbonate cementation in a sequence-stratigraphic framework: Upper Cretaceous sandstones, Book Cliffs, Utah-Colorado[J]. Journal of sedimentary research, 2000,70(2):360～372
[19]	Kantorowicz J D, Bryant I D, and Dawans J M. Controls on the geometry and distribution of carbonate cements in Jurassic sandstones: Bridport Sands, southern England and Viking Group,Troll Field, Norway[A]. In: Marshall J D, ed. Diagenesis of Sedimentary Sequences: Geological Society of London, Special Publication,1987,36: 103～118
[20]	徐北煤, 卢冰. 硅质碎屑岩中碳酸盐胶结物及其对储层的控制作用的研究[J]. 沉积学报, 1994, 12(3): 56～66[Xu Beimei, Lu Bing, The study of diagenetic carbonate in siliciclastic rock and its control in the reservoir[J].Acta Sedimentologica Sinica, 1994,6(4): 56～66]
[21]	McArthur J M, Howarth R J, Bailey T R. Strontium Isotope Stratigraphy: LOWESS Version 3: Best Fit to the Marine Sr-Isotope Curve for 0～509 Ma and Accompanying Look-up Table for Deriving Numerical Age[J]. J. Geol., 2001,109:155～170
[22]	Veizer J, Ala D, Azmy K, Bruckschen P, Buhl D, Bruhn F, Garden G A F,et al. 87 Sr/ 86 Sr, δ¹³C and δ^18O evolution of Phanerozoic seawater[J]. Chem. Geol., 1999,161:59～88
[23]	Palmer M R, Edmond J M. The strontium isotopic budget of the modern ocean[J]. Earth Planet.Sci. Lett., 1994,92:11～26
[24]	Veizer J, Fritz P,Jones B. Geochemistry of brachiopods: Oxygen and carbon isotope records of Paleozoic oceans[J]. Geochim. Cosmochim. Acta. 1986, 50: 1 679～1 696
[25]	黄思静. 海相碳酸盐矿物的阴极发光性与其成岩蚀变的关系[J]. 岩相古地理, 1990, 4: 9～15[Huang Sijing.Cathodoluminescence and diagenetic alteration of marine carbonate minerals[J]. Sedimentary Facies and Palaeogeography,1990.(4): 9～15]
[26]	Palmer A R,Geissman J. Geologic time scale. The Geological Society of America, Product code CTS004,1999
[27]	朱国华. 陕北延长组成岩圈闭油藏的形成及其重要意义[J]. 沉积学报, 1988,6(4): 1～11[Zhu Guohua. Formation of diagenetic trapping reservoir of Yan Chang Formation, in Northern Shaanxi and its Significance[J]. Acta Sedimentologica Sinica,1988, 6(4): 1～11]
[28]	Qing H, Barnes C R, Buhl D and Veizer J. The strontium isotopic composition of Ordovician and Silurian brachiopods and conodonts: Relationships to geological events and implications for coeval seawater[J]. Geochim. Cosmochim. Acta, 1998,62(10): 1 721～1 733

Application of Strontium Isotope Stratigraphy to Diagenesis Research

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