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Wu Xhijun, Luo Binjie, Wang Youxiao, Wang Chunjiang, Meng Qianxiang, Li Yulan. Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types[J]. Acta Sedimentologica Sinica, 1995, 13(3): 98-106.
Citation: Wu Xhijun, Luo Binjie, Wang Youxiao, Wang Chunjiang, Meng Qianxiang, Li Yulan. Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types[J]. Acta Sedimentologica Sinica, 1995, 13(3): 98-106.

Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types

  • Received Date: 1994-05-05
  • Publish Date: 1995-09-10
  • Commercial oils drilled in most parts of the North Tarim Uplift and Central Tarim Uplift have been characterized and corn firmed as oils derived from marine Lower Paleozoic source rocks. The marine oils might have, however, originated from blask shale beds or carbonate sequences of the same age. That brings difficulties in oil-source correlation by biomaker approaches. In this paper, dibenzothiophene distributions of typical marine carbonate-sourced oils and siliciclanic sourced oils with different maturity have been studied in detail. It is revealed that the dibenzothiophene demethylation index(DDI) and dibenzothiophene methyl-isomeration index(DMI) could distinguish two types of oils effectively and suffer from little influence of maturity. According to the relative amounts of DBTS and DDI vs DMI values of Tarim oils, the major source rocks in Tarim Basin are identified as the dark and black laminated micrite and marlite deposited in the Ordovician continental shelf zone.
  • [1] 1.Goldstein T. P.,1983, Geacatalytic reaMions in formation and maturation of petroleum, AAPG Bulletin, Vol. 67,No. 1.P.152-159.

    2.Hughs W. B.,1984, Use of thiophenic organosulfur compounds in characterizing crude oils derived from carbonate versussiliciclastic sources. In Petroleum Geochemistry and Source Rock Potential of Carbonate Rocks(F.dited by Palaces I. G.).AAPG Stud. Geol. 18. 181一196. Am Assoc. Pet. Geol.,Tuh;i.OK.

    3.Sinninghe jeep S. 1Jamste and Jan W. Ik Leeuw, 1990,Analysis, structure and geochemical significance of or}nically boundsulphur in geosphere; State of the art and future research. In Advances of Orgpnic Geochemistry. Vol. 16.No. 5. 4^-6,P1077-1101.Peranmnn Press.

    4.贾承造,姚慧君等.1991,塔里木盆地板块构造演化和主要构造单元地质特征,塔里木盆地油气勘探论文集,童晓光,梁狄刚主编,乌鲁木齐:新吸科技卫生出版社,207-225。

    5.盛国英,傅家漠.S. C. Brassel. G. Eglinton和江继纲.1986,青盐盆地高硫原油中的长链烷基唾吩类化合物,地球化学,(2):138-146。

    6.应光国,范璞,1992.美国南佛罗里达盆地Sunniland组原油和油源岩中芳烃的有机地球化学研究,沉积学报,10(2):126-134。
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  • Received:  1994-05-05
  • Published:  1995-09-10

Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types

Abstract: Commercial oils drilled in most parts of the North Tarim Uplift and Central Tarim Uplift have been characterized and corn firmed as oils derived from marine Lower Paleozoic source rocks. The marine oils might have, however, originated from blask shale beds or carbonate sequences of the same age. That brings difficulties in oil-source correlation by biomaker approaches. In this paper, dibenzothiophene distributions of typical marine carbonate-sourced oils and siliciclanic sourced oils with different maturity have been studied in detail. It is revealed that the dibenzothiophene demethylation index(DDI) and dibenzothiophene methyl-isomeration index(DMI) could distinguish two types of oils effectively and suffer from little influence of maturity. According to the relative amounts of DBTS and DDI vs DMI values of Tarim oils, the major source rocks in Tarim Basin are identified as the dark and black laminated micrite and marlite deposited in the Ordovician continental shelf zone.

Wu Xhijun, Luo Binjie, Wang Youxiao, Wang Chunjiang, Meng Qianxiang, Li Yulan. Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types[J]. Acta Sedimentologica Sinica, 1995, 13(3): 98-106.
Citation: Wu Xhijun, Luo Binjie, Wang Youxiao, Wang Chunjiang, Meng Qianxiang, Li Yulan. Distribution of Dibenzothiophenes in Crude Oils from Tarim Basin and Identification of Major Source Rock Types[J]. Acta Sedimentologica Sinica, 1995, 13(3): 98-106.
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