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SJPC19-3沉积岩心三个沉积物样品AMS 14C年代测试结果表1所示。岩心从顶部至底部年代由新变老,岩心顶部10 cm处年代为1 995~1 999 A.D.,底部年代约为980~1 052 A.D.。已有研究发现升金湖沉积岩心基本无碳库效应[37],因此该岩心完整覆盖升金湖地区约过去一千年水文变化。本研究根据三个年代数据进行二次多项式拟合,建立岩心最终的年代—深度序列[37](图2)。
样品编号 深度/cm 测年材料 AMS14C年龄(2σ)/a B.P. 校正后日历 年龄/A.D. SJPC19-315 10 植物残体 -48±2 1 995~1 999 SJPC19-3-70 45 植物残体 550±30 1 386~1 434 SJPC19-3-111 86 总有机质 990±30 989~1 052 -
通过对SJPC19-3孔XRF岩心扫描得到的Ti、Cr、Sr、CaO、Rb/Sr、SiO2含量变化进行描述(图3);Ti含量波动范围为4 800~6 000 mg/kg,平均为5 529 mg/kg;Rb/Sr波动范围为2~8,平均为5.13;Sr含量波动范围在15~60 mg/kg,平均为24.60 mg/kg;Cr含量波动范围在70~98 mg/kg,平均为83.77 mg/kg;SiO2含量波动范围在56%~62%,平均为59.57%;CaO含量波动范围在0~5%,平均为1.38%。
总体来看,升金湖沉积岩心Ti、Cr、SiO2、Rb/Sr变化趋势大致相似,高强度值出现在约1 000~1 100 A.D.与1 300~1 600 A.D.之间,且后一阶段波动强度较前一阶段显著,在1 600 A.D.之前含量较高,1 600 A.D.之后含量相对较低,在1 850 A.D.以来有上升的趋势;元素Sr、CaO含量总体变化趋势大致相同,1 600 A.D.之前含量相对较低,1 600 A.D.之后含量相对较高。在1 000~1 350 A.D.元素Sr、CaO含量保持在低值范围,在约1 100 A.D.元素Sr、CaO含量为岩心最高值,在1 350~1 850 A.D.元素Sr、CaO含量由低值向高值变化,1 850 A.D.以来,元素Sr、CaO含量呈显著下降趋势。
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沉积物中TOC、TN、C/N、IC测定结果显示(图4),TOC含量波动范围为0.5%~2.5%,平均为1.349%;TN含量波动范围为0.05%~0.25%,平均为0.156%;C/N波动范围为5~15,平均为8.433;IC含量波动范围为0~1.5%,平均为0.183%。TOC、TN和C/N过去千年呈波动增加趋势,在1 000~1 600 A.D.期间TOC、C/N与TN含量缓慢波动增加,在1 600~1 650 A.D.期间迅速增加,之后保持在高值水平;在1 350 A.D.前,IC含量呈波动变化并以1 100~1 150 A.D.较为显著,1 350~1 600 A.D.时段接近0值,1 600~1 850 A.D.期间IC为岩心最高值水平,1 850 A.D.以来呈显著降低趋势[37]。
3.1. 年代—深度序列
3.2. XRF元素扫描结果
3.3. 总有机碳、总氮、碳氮比、无机碳测定结果
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