四川邻水高滩镇地热井含膏盐段岩屑碳氧同位素特征及意义
- 1. 中国地质调查局成都地质调查中心(西南地质科技创新中心)
- 2. 成都地质矿产研究所
- 收稿日期:
2023-08-28
- 网络出版日期:
2024-03-08
摘要: 碳、氧同位素是碳酸盐岩重要的地球化学指标之一,在揭示沉积、成岩流体特征方面发挥着重要作用,已成为人们研究碳酸盐岩的基本手段之一。目前,国内外已开展了大量石灰岩-白云岩阶段的碳、氧同位素研究,但对于硫酸盐-碳酸盐阶段的碳、氧同位素研究较少。沉积序列中的硫酸盐-碳酸盐阶段,仍有可供测试的碳、氧元素,为此项研究提供了可能。目前已有华蓥山地表三叠系膏盐段及澳大利亚Reichenhall含膏地层的碳、氧同位素研究,但这些研究较少且均集中在地表样品。开展地腹膏盐样品碳、氧同位素的研究具有重要的理论意义。在四川盆地华蓥山东侧四川邻水县高滩镇倒碑村地热井钻进过程中,以嘉陵江组-雷口坡组膏盐夹层岩屑为研究对象,开展了碳、氧同位素研究,结果表明:(1)倒碑地热井膏盐夹层岩屑δ18OPDB(‰)介于-2.56~-15.47,均值-9.13。δ13CPDB(‰)介于-4.68~-0.12,平均值-2.86,Z值普遍低于120,与其海相沉积的特征不符。δ18OPDB、δ13CPDB值明显低于华蓥山地表三叠系膏盐地层及澳大利亚Reichenhall膏盐地层;(2)该区膏盐地层碳、氧同位素主要受到地层褶皱前深埋阶段热化学硫酸岩还原作用(TSR)作用以及地层褶皱、断裂、抬升后地表淡水的大量灌入影响。地层褶皱前较高的地层温度和有机碳的交换,以及褶皱、断裂后地表水的淡化,是导致该区膏盐层δ18O、δ13C偏低的根本原因。在沉积阶段,可能有少许淡水作用和影响;(3)根据Craig(1965)方程计算的地层温度28.18~111.71℃,平均68.45℃。根据Vasconcelos(2005)方程计算的地层温度4.54℃~78.21℃,均值38.91℃。前者接近地层现今温度,后者偏低可能与计算公式δ18O的取值有关。
Carbon and oxygen isotope characteristics and it’s significance of rock debris in the salt-bearing section of geothermal well in Gaotan Town, Linshui County, Sichuan Province
- Received Date:
2023-08-28
- Available Online:
2024-03-08
Abstract: Carbon and oxygen isotopes are one of the important geochemical indexes of carbonate rocks, which play an important role in revealing the characteristics of sedimentary and diagenetic fluids, and have become one of the basic means to study carbonate rocks. At present, a large number of studies on carbon and oxygen isotopes in limestone-dolomite stage have been carried out at home and abroad, but there are few studies on carbon and oxygen isotopes in sulfate-carbonate stage. In the sulfate-carbonate stage of the sedimentary sequence, there are still carbon and oxygen elements that can be tested, which makes this study possible. There are currently studies on carbon and oxygen isotopes of the plaster salt section of Huaying Mountain and the plaster bearing strata of Reichenhall Formation, Australia, but these studies are few and concentrated on surface samples. It is of great theoretical significance to study carbon and oxygen isotopes of underground paste and salt samples. In the process of drilling geothermal well in Doubei Village, Gaotan Town, Linshui County, Sichuan, to the east of Huaying Mountain in Sichuan Basin, carbon and oxygen isotopes of paste salt interbedding cuttings of Jialingjiang-Lekoupo Formation were studied. It is concluded that :(1) The δ18OPDB (‰) of paste salt interbedding cuttings in the Daobei geothermal well ranges from -2.56 to -15.47, with an average value of -9.13. The δ13CPDB (‰) ranges from -4.68 to -0.12, with an average value of -2.86, and the Z-value is generally lower than 120, which is inconsistent with the characteristics of Marine sediments. The δ18OPDB and δ13CPDB values were significantly lower than that of the Triassic paste salt formation in Huaying Mountain and the Reichenhall paste salt formation in Australia; (2) The carbon and oxygen isotopes of the underground salt-salt strata in this area are mainly affected by the thermochemical sulfate reduction (TSR) in the deep-buried stage before the formation fold and the massive inflow of surface fresh water after the formation fold, fracture and uplift. The high formation temperature and the exchange of organic carbon before fold and the desalting of surface water after fold and fracture are the fundamental reasons for the low δ18O and δ13C of the gypsum salt layer in this area. At the same time, there may be a little freshwater action and influence during the depositional stage; (3) The formation temperature calculated by Craig'sequation (1965) was 28.18~111.71℃, with an average of 68.45℃. The formation temperature calculated by Vasconcelos'sequation (2005) ranges from 4.54℃ to 78.21℃, with an average value of 38.91℃. The former is close to the present temperature of the formation, while the latter is lower, which may be related to the selection of δ18O in the calculation formula.
刘建清, 黄从俊, 朱华平, 何利, 冉敬. 四川邻水高滩镇地热井含膏盐段岩屑碳氧同位素特征及意义[J]. 沉积学报. doi: 10.14027/j.issn.1000-0550.2024.015
Carbon and oxygen isotope characteristics and it’s significance of rock debris in the salt-bearing section of geothermal well in Gaotan Town, Linshui County, Sichuan Province[J]. Acta Sedimentologica Sinica. doi: 10.14027/j.issn.1000-0550.2024.015
Citation: |
Carbon and oxygen isotope characteristics and it’s significance of rock debris in the salt-bearing section of geothermal well in Gaotan Town, Linshui County, Sichuan Province[J]. Acta Sedimentologica Sinica. doi: 10.14027/j.issn.1000-0550.2024.015
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