川南茅一段白云石化过程及其对眼球状灰岩形成的指示——以DB1井为例
- 收稿日期:
2023-12-18
- 网络出版日期:
2024-04-22
摘要: 【目的】灰岩-泥灰岩韵律层作为气候、水文以及地质事件的载体,是地质学者的重点研究对象,但四川盆地茅一段眼球状灰岩的成因一直存在争议。DB1井茅一段眼球状灰岩中发育准同生-早成岩期白云石化,可以较好限制碳酸盐岩的沉积环境。【方法】通过对DB1井茅一段云质岩类系统的岩石学和地球化学分析讨论云化流体和云化过程。【结果】DB1井茅一段存在三种云质岩类,眼皮状云质灰岩(I,泥质云岩)发育准同生期溶蚀孔,阴极发光环带发育,具有平坦型稀土配分模式,较高的δ13C、δ18O值以及低于海水的Y/Ho,是少量大气淡水混合海水在准同生期云化形成;眼皮状云质灰岩(II,灰质云岩)具有左倾型稀土配分模式,与同沉积海水一致的δ13C、δ18O、87Sr/86Sr和Y/Ho,为弱蒸发的海水在同沉积期-准同生阶段云化而成;眼球状云质灰岩(含云质灰岩)具有左倾型稀土配分模式,较高的δ13C、δ18O值,近似海水的Y/Ho,是孔隙水在早成岩阶段云化而成。【结论】茅一段准同生-早成岩期云化限制了其沉积时的水体环境较浅。此外以眼皮为主的层段具有更高的泥质含量和锶同位素值,以及更低的碳氧同位素和Y/Ho,表明以眼皮为主的层段沉积时的水体更浅。
The process of dolomitic in the Member I of the Maokou Formation, the southern Sichuan basin, and its indication for the formation of the eyelid-eyeball limestone-a case of DB1 well
- Received Date:
2023-12-18
- Available Online:
2024-04-22
Abstract: [Objective]The limestone-marlstone alterations (LMAs) are the important archives of climatic, hydrological, and geological events for geologists. But as a typical endmember of the LMAs, the knowledge about the genesis of the LMAs with eyelid-eyeball structure of the Member I of the Maokou Formation in the Sichuan Basin has not come to agreement widely. This not only seriously affects environmental researching of the LMAs with eyelid-eyeball structure, but also affects the efficiency of its exploration. Dolomitization is developed in the LMAs with eyelid-eyeball structure (mainly in the eyelids) of the Member I of the Maokou Formation of the DB1 well during the penecontemporaneous and early diagenetic phase can be used to constrain the depositional environments of carbonate rocks. [Methods] In this paper, petrological and geochemical analyses have been carried out in detailed, the process and the fluid properties of dolomitization has been discussed to constrain the process of LMAs with eyelid-eyeball structure. [Results and Discussions]Three types of dolomitization are developed in the Member I of the Maokou Formation, which are muddy dolomitic (EDM-I); limy dolomitic (EDM-II) and dolomitic marlstone(EDL). EDM-I has the highest degree of dolomitization, distinct bands of cathodoluminescence, a flat rare earth partitioning pattern, higher δ13C and δ18O values but lower Y/Ho values relative to seawater, it was dolomitized by penecontemporaneous seawater mixed with a small amount of meteoric freshwater during the penecontemporaneous phase. EDM-II has the middle degree of dolomitization, a left leaning rare earth partitioning pattern and values of δ13C, δ18O, 87Sr/86Sr, and Y/Ho similar to seawater, it was dolomitized by seawater with high Mg/Ca, which was induced by frequent sea-level rise and fall changes during the syn-sedimentary and penecontemporaneous phase. EDL has the lowest degree of dolomitization, a left leaning rare earth partitioning pattern, higher δ13C and δ18O values relative to EDM-II, and seawater-like Y/Ho values. EDL was dolomitized by the sealed seawater of the syn-sedimentary phase which has been alterated with the wall rocks in the early diagenetic stage. [Conclusions] The dolomitization of the LMAs with eyelid-eyeball structure by weakly evaporating seawater and seawater mixed with freshwater during the penecontemporaneous and early diagenetic phase requires that the LMAs deposited in a shallower water. The high mud content, high strontium isotope and rare earth element values, low carbon and oxygen isotope values and Y/Ho values of the eyelid-like marlstone relative to the eyeball-like limestone indicate that the depth of water for the eyelid-like marlstone is shallower than that of the eyeball-like limestone during they deposited. Therefore, it is inferred that the LMAs in the Member I of the Maokou Formation were produced under cyclic oscillation in the depositional environment, and their genesis may have been mainly influenced by sedimentary process.