Carbon and Hydrogen Isotopic Composition of Individual nAlkanes for Crude Oil from North Margin of Qaidam Basin
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摘要: 以柴达木盆地北缘不同构造带代表性原油作为研究对象,采用GC—TC—IRMS技术对原油中正构烷烃单体碳、氢同位素进行测定。利用样品正构烷烃单体碳、氢同位素组成特征及分布模式,进行原油成因类型划分和对比分析。研究结果表明,正构烷烃可溶有机质的δ13C分布在-36‰~-25‰,δD分布在-180‰~-110‰。对比发现,不同构造带原油中正构烷烃单体碳、氢同位素组成特征上存在着比较明显的差别。以-30‰(δ13C)和 -140‰(δD)作为分界,结合同位素曲线的分布型式,可以划分为不同的分布模式判识生烃母质和沉积环境。
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关键词:
- 单体正构烷烃  /
- 碳同位素  /
- 氢同位素  /
- 生物标记化合物  /
- 柴达木盆地北缘
Abstract: Using GC/C/MS online carbon isotope analysis technique, we obtained the carbon and hydrogen isotopic composition of individual nalkanes for crude oil from different tectonic belts of the north margin of Qaidam Basin. The carbon and hydrogen isotopic composition of nalkanes for crude oil samples can be used to analyze genetic type of crude oil and oilsource correlation. The analytical results indicate that the δ13C and δD values of nalkanes in soluble organic matter ranging between 36‰~25‰ and 180‰~110‰, respectively. Through comparing, it is found that there exist significant differences between the carbon and hydrogen isotopic composition of nalkanes for crude oil from different tectonic belts. By the combination of δ13Cnalkanes (30‰), δDnalkanes (140‰), and distribution pattern isotopic curve, the carbon and hydrogen isotopic composition can be divided into different distribution patterns. Using these patterns can discriminate hydrocarbon generation material and sedimentary environment.-
Key words:
- n alkanes /
- carbon isotopes /
- hydrogen isotopes /
- biological markers /
- north margin of Qaidam Basin
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