Hydrocarbon Generation Mechanism and Evolution Characteristics of Biomarkers on LowEvolutionary Source Rocks of the Salt Lacustrine Facies
-
摘要: 柴达木盆地盐湖相低演化烃源岩沥青“A”的热模拟研究表明:在热作用下其排烃高峰在热模拟温度较低区间220~270℃,且以非烃和沥青质相对丰度最高为特征。沥青“A”在由未熟—低熟—成熟的演化过程中,各系列生物标志物的成熟速率不同,表现为正构烷烃>藿烷>甾烷。非烃和沥青质中含杂原子的极性化合物在热模拟温度300℃后开始大量发生脱羟基、脱羧基、脱羰基及链断裂反应。沉积有机质在低演化阶段甾烷C29ββ/(ββ+αα)值异常高表明该地区细菌微生物发育。柴达木盆地低演化烃源岩在较低温度区间大量排烃,是细菌微生物对沉积有机质改造后其活化能大大降低所致。
-
关键词:
- 化烃源岩热模拟生烃机理生物标志物
Abstract: Investigation of the thermal simulation of lowevolutionary source rocks bitumen “A” of the salt lacustrine facies in Qaidam Basin indicated that the range of temperature on the hydrocarbon generating fastigium in the thermal function are 200~270℃, and the source rocks are characterized by high relative abundance of the nonhydrocarbon and asphaltene. The mature velocity of the biomarkers are different from the immature to lowmature to highmature oil, and it’s sequence is alkane>hopane>sterane. The polar compound in the nonhydrocarbon and asphaltene, which have some atom other than carbon, have some reactions after 300℃ in thermal simulation, for instance, dehydroxylation, decarboxylation, decarbonyl and the chain cleavage. The ratio of sterane C29ββ/(ββ+αα) is very high in lowevolutionary stage, indicating that there are some bacteriumgerms in this area. In low temperature range of lowevolutionary source rocks in Qaidam Basin have generated a significant volume of hydrocarbon, consequently the activation energy of source rocks would become down because the depositional organic matter have been rebuilt by the bacteriumgerms.-
Key words:
- lowevolutionary source rocks
-

计量
- 文章访问数: 1773
- HTML全文浏览量: 10
- PDF下载量: 645
- 被引次数: 0