Length-Slow Chalcedony in Chrysanthemum Stone of Chihsia Formation, South China and Its Geological Implications
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摘要: 正延性玉髓常被视为干旱蒸发沉积环境的标志。正延性玉髓亦广泛分布于华南地区栖霞组菊花石 (目前绝大多数为天青石假象 )内。本文在天青石后期矿物交代序列识别的基础上,通过对菊花石内各期次碳酸盐交代矿物的电子探针分析,发现菊花石内正延性玉髓形成于富含硫酸根离子和镁离子的成岩介质条件中。结合已有的正延性玉髓研究报道和栖霞组的沉积、成岩作用环境特征分析,认为华南地区栖霞组菊花石内正延性玉髓的形成环境与高蒸发沉积环境或高盐度成岩环境无关。因此,仅根据正延性玉髓的出现不足以确定沉积或成岩环境的盐度条件。Abstract: Length slow chalcedony (LSC) was commonly used as an indicator of evaporitional environments. LSC was also distributed widely in the chrysanthemum stone, the pseudomorph of a kind of nodular celestite, from the Permian Chihsia Formation of South China. A number of lines of evidence indicated the Chihsia Formation was accumulated in a shallow carbonate platform with normal salinity. Based on microscopic observation, a comprehensive replacement succession has been established for the celestite pseudomorph as: celestite(fine-grained cloudy calcite(LSC) (Fig.Ⅰ B, C, D)(clear granular calcite(euhedral calcite crystal (in LSC) (Fig.Ⅰ B)(clear calcite (Fig.Ⅰ C). The original celestite has also been replaced directly by LSC at places. The latest generation of coarse calcite is related to calcite vein (Fig.Ⅰ C). Electronic microprobe analysis on the replacement calcites (Table 1) shows higher magnesium content in the replacement calcites of early phase ( including fine grained cloudy calcite and clear granular calcite) than those of later phase, indicating a magnesium rich diagenetic environment. In addition, tiny celestite detected by electronic scanning microscope in the replacement calcites of early phase and strontianite in the replacement calcite of later phase indicate the geochemical compositional transition of diagenetic fluids from sulfate rich to carbonate rich. The LSC was thus formed in a fluid rich in sulfate and magnesium, agreeing well with reported cases from evaporitional and non evaporitional environments. The possibility of evaporitional sedimentary environments or saline diagenetic conditions favoring the formation of LSC, thus, was excluded for the Chihsian LSC. The LSC should not be used, by itself, as a reliable indicator of evaporitional environment of deposition.
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Key words:
- Chihsia Formation /
- cheysanthemum stone /
- length-slow chalcedony
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[1] 1.Folk R L;Pittman JS Length-slow chalcedony:a new testment for vanished evaporites 1971(04)
2.Florke O W;Graetsch H;Martin B Nomenclature of micro-and non. crystalline siica minerals,based on structure and microstructure 1991
3.Heaney P J;Post J E The widespread distribution of a novel silica polymorph in microcrystalline quartz varoetoes 1992
4.Siedlecka A Length-slow chalcedony and relicts of sulphets-evidences of evaporitic environments inthe Upper Carboniferous and Permian beds of Bear Island, Svalbard 1972(04)
5.West I Vanished evaporites-significance of strontium minerals 1973(01)
6.Chowns T M;ElkinsJE The origin of quartz geodes and cauliflower cherts through the silicffication of anhydrite nodules 1974(03)
7.Tucker M E Replaced evaporites from the Precambrian of Finnmark,Arctic Norway 1976
8.Tucker M Quartz replaced anhyddte nodules ("Bristol Diam onds”)from the Triassic of the Bristol District 1976(06)
9.Millilen K L The silicified evaporites syndrome-two aspects of silici-fication history of former evaporite nsodules frcm southern Kentucky andnorthern Tennessee 1979(01)
10.Shukla V;Friedman GM Anunusual occurrence of surficial anhy-drite in a moist temperate zone:example from the Lockport Formation (Middle Silurian) of New York 1981
11.Elorza J;Rodriguez- Lazaro J Late Cretaceous Quartz geodes after anhydrite from Burgos,Spain1984(02)
12.Maliva R G Quartz Geodes: Early diagenetic silicified anhydrite nod-ules related to dokomitization 1987(06)
13.秦震重庆地区天青石型锶矿床成矿特征 1998(25)
14.Ross G M;Chiarenzelli J R Paleoclimatic significance of widespread Proterozoic silcretes in the Bear and Churchill Provinces of the northe-western Canadian Shield 1985(02)
15.Length-slow chalced onyinsedimentaryrocksoftheMeso-zoic allochthonous terrane in central Japan and its use for tectonic syn-thesis
16.JackaAD Replacement of fossils by length- slow chalcedony and as-sociated dolomitization1974(02)
17.Keene J B Chalcedonic quartz and occurrence of quartzine (length-slow chalcedny) in pelagic sediments 1983
18.StronRN;Upchurch S B;Rosenzweig A Paragenesis of "box-workGeodes”, Tampa Bay,Florida 1981
19.Fang YS;Yuan X Y Discovery of the chrysanthemum-shaped ce-lestite in the Perrnian carbonates ofPingxian-Leping Depression of Jiangxi Province 1991(36)
20.朱嗣昭;方邺森;袁旭音赣西湘东地区下二叠统称沉积中水玉髓的研究 1995
21.XuHF;BuseckPR;Luo G F HRTEM investigation of microstruc-tures in length-slow chalcedony 1998
22.沙庆安;吴望始;傅家谟黔桂地区二叠系综合研究-兼论含油气性.!!北京:科学出版社 1990
23.周怀玲;张振贤广西二叠纪的菊花石 1994(07)
24.颜佳新;杜远生冰川发育对赤道地区碳酸盐沉积环境和沉积作用的影响 1994(03)
25.颜佳新;方念乔湖北省栖霞组沉积环境,沉积旋回及层序地层划分 1994(19)
26.颜佳新;陈北岳;李思田鄂湘桂地区栖霞组古氧相分析与层序地层和海平面变化[期刊论文]-地质论评 1997(43)
27.颜佳新;徐四平;李方林湖北巴东栖霞组缺氧沉积环境的地球化学特征 1998(06)
28.颜佳新;赵锡文;杜远生利用群落古生态分析研究黄石地区栖霞组沉积环境 1996(16)
29.Ziegler A M;Gibbs M T;Barns WS Oceanic water masses in the Permian Period 1997
30.冯增昭中下扬子地区二叠纪岩相古地理 1991
31.颜佳新;伍明;李方林湖北省巴东栖霞组沉积成岩作用地球化学特征研究 1998(04)
32.Baker P A;Bloomer S H The origin of celestite in deep-sea car-bonate sediments[外文期刊] 1988(02)
33.Haffield CB Discussion: replacement of fossils by length- slow chal-cedony and associateddolmitization: by A D Jacka, J. Sed. Petrolo-gy, 44:421~427 1975
34.Folk R L Third-party reply to Hatfield: Disussion of Jacka A D,1974, Fossils by length-slow chalcedony and associated dolomitization:Sed. Petrology,44, 421~427 1975
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