Discriminant Effect of Sedimentary Environment by the Sr/Ba Ratio of Different Exising Forms
-
摘要: 锶钡比是常用的沉积环境判别标志之一。通常以Sr/Ba大于或小于1来判别海、陆相沉积环境,但实际应用过程中相互矛盾甚至相反现象的出现,使得人们对这一指标的可靠性产生了怀疑甚至否定。本文对现代黄河三角洲不同沉积环境的全样锶钡比(Sr/Ba)T和稀盐酸可溶性锶钡比(Sr/Ba)A进行了对比研究,结果表明,(Sr/Ba)T对沉积环境的变化反映不明显,而(Sr/Ba)A则具有明显的指相性,并认为前者是由于大量赋存于陆源碎屑矿物(如长石等)中的锶钡的掩蔽所致。Abstract: The ratio of strontium to barium is a universal indicator for distinguishing depositional environments. Usually, the value of Sr/Ba more or less than 1 should be responsible for marine or continental deposit, respectively. However, the authenticity of this indicator has nowadays been suspected, even negated by most of sedimentologists and geochemists because of some contradictions or opposite explanations with geological facts. By comparison study of the ratio of (Sr/Ba)Tratio of total Sr to total Ba in bulk sediment analysis, and the ratio of (Sr/Ba)A ratio of dissolvable Sr to dissolvable Ba that were extracted in dilute hydrochloric acid from the different environment of the modern Yellow (Huanghe) river delta in this paper, it is suggested that the ratio of (Sr/Ba)T is not sensitive for environment variation while the (Sr/Ba) Ashows the sensitive diversity with different sedimentary environments and, moreover,the former results are unreliable because of the disturbance of bulk Sr Ba exiting in terrigenous minerals (for example, feldspar, biotite, ect.) over the Sr and Ba formed in sedimentation. Finally, an attempt is made to evaluate the method of distinguishing sedimentary environments in use of the ratio of strontium to barium.
-
[1] (1) 南京大学地质系. 地球化学. 北京: 科学出版社, 1984, 357-358.
(2) 刘英俊等. 元素地球化学. 北京: 科学出版社, 1984, 360-372.
(3) 刘宝 王君. 沉积岩石学. 北京: 地质出版社, 1980, 286-289.
(4) 同济大学海洋地质系. 海、 陆相地层辨认标志. 北京: 科学出版社, 1980, 159-164.
(5) 杨作升等. 黄河口毗邻海域细粒沉积物特征及沉积物入海后的运移. 山东海洋学院学报, 1985, 15 (2): 121 —128.
(6) 黎彤, 郭范. 元素丰度表. 北京: 地质与勘探编辑部出版, 1981.
(7) Wedepohl K H. Handbook of Geochemistry. 1987, 2/5 B.
(8) 吴明清, 王贤觉. 东海沉积物的稀土和微量元素. 地球化学, 1991, (1): 40-46.
(9) 刘岫峰. 沉积岩实验室研究方法. 北京: 地质出版社, 1991, 206-207.
(10) 郑光膺. 南黄海第四纪层型地层对比. 北京: 科学出版社, 1989.
(11) Tessier A, et al. Sequential ex traction procedure for the speciation of particulate trace metals. Analytical chem-istry, 1979, 51 (7):844-851.
(12) 杨鲁成等. 中国若干主要河流和浅海沉积物中痕量元素总量及 HCl提取量的研究. 环境地球化学与健康, 贵阳:贵州科学技术出版社, 1990, 250-251. -

计量
- 文章访问数: 679
- HTML全文浏览量: 72
- PDF下载量: 461
- 被引次数: 0