用显微荧光和显微傅立叶红外光谱研究显微组分的热演化规律
-
摘要:
镜质体反射率是确定油源岩成熟度最广泛使用的参数,显微荧光强度及其变化也已成为检测烃源岩有机质生烃尤其是生油的标志之一,而红外光谱在研究生油母质干酪根的结构、类型和生烃潜力等方面均取得了大量的研究成果,特别是傅立叶红外显微镜的问世,给单显微组分提供了一种有效的研究手段。本文应用上述方法对一套人工熟化样品进行了检测和分析,探讨了显微组分的光性演变特征和化学成分的变化规律,并建立了显微组分的生油模式。
Abstract:镜质体反射率是确定油源岩成熟度最广泛使用的参数,显微荧光强度及其变化也已成为检测烃源岩有机质生烃尤其是生油的标志之一,而红外光谱在研究生油母质干酪根的结构、类型和生烃潜力等方面均取得了大量的研究成果,特别是傅立叶红外显微镜的问世,给单显微组分提供了一种有效的研究手段。本文应用上述方法对一套人工熟化样品进行了检测和分析,探讨了显微组分的光性演变特征和化学成分的变化规律,并建立了显微组分的生油模式。
-
Key words:
- microfluorescence /
- FTIR microspectroscopy /
- maceral /
- oil-generating model
-
[1] 1.Teichmuller M and Wolf M. Application of fluorescence microscopy in coal petrology and oil exploration. J Mi-croscopy, 1977, 109: 49— 73.
2.Teichmuller M and Ottenjann K. Art und Diagenese v on Liptiniten und Lipoiden stoffen in einem Erdolmut-teryestein auf Grund fluoreszenzmidroskopischer untersuchungen. Erdol u kohle, 1977, 30: 387-398.
3.Teichmller M. Application of coal petrological methods in g eology including oil and gas prospecting, In: Stach,E (Editor ), Stach's Tex tbook of coal petrology. Berlin, 1982, 381-413.
4.Robert P. The optical evolution of kerogen and geo thermal histories applied to oil and gas ex ploration. In: Durand,B (Editor), kerogen, Technip, Paris, 1980, 385-414.
5. Alpern B. The petrolog y of kerogen. In: Durand, B (Editor ), Kerog en, Technip, paris, 1980, 284-321.
6.Hotton A C. Organic matter in oil shale. APEA J, Sydhey, N SW, 1980, 20:44— 63.
7. Pradier B, et al. Chemical basis of fluorescence alteration of crude oils and kerog ens- Ⅱ. Fluorescence and infraredmicro-spectrometric analysis of vitrinite and Liptinite. Org Geochem, 1992, 18 (3): 241-248.
8.Ganz H H. Application of infrared spectroscopy to the classification of kerog en types and the evaluation of sourcerock and oil shale potentials. Fuel, 1987, 66.
9.Jacky Kister, et al. Characterization of chemical structure, degree of maturation and oil potential of quantitativeFTIR spectroscopy. Fuel, 1990, 69.
10.董庆年. 煤结构研究中的傅立叶变换红外光谱. 见: 《近代傅立叶变换红外光谱技术及应用》, 吴瑾光主编, 科学技术文献出版社, 北京: 1994, 63-88.
11.Rui Lin, et al. Studying individual macerals using i. r. microspectroscopy and implications on oil versus gas / con-densate proneness and “ Low - rank ” g eneration. Org Geochem, 1993, 20 (6):695-706.
12.Alpern B. Detection and evalution of hydrocarbons in source rocks by fluo rescence microscopy. Org Geochem,1993, 20 (6): 789— 795.
13.Durand B (Editor). kerogen. 中译本, 100-119.
14.肖贤明著. 有机岩石学及其在油气评价中的应用. 广东科技出版社, 1992, 105-109 。
计量
- 文章访问数: 582
- HTML全文浏览量: 31
- PDF下载量: 501
- 被引次数: 0