青海湖沉积物支链和环烷烃组分中C20，C25和C30高度支链类异戊二烯烯烃

李景贵; 范璞; 崔明中; 李振西; R. P. Philp; J. Allen

青海湖沉积物支链和环烷烃组分中C₂₀，C₂₅和C₃₀高度支链类异戊二烯烯烃

1 中国科学院兰州地质研究所兰州 730000;
2 University of Oklahoma, School of Geology and Geophysics, Norman, OK 73019 USA

基金项目: 中国科学院兰州分院（1994）部分资助。

详细信息

作者简介:
李景贵,52岁,副研究员,有机地球化学

计量

文章访问数: 560
HTML全文浏览量: 22
PDF下载量: 311
被引次数: 0

C₂₀, C₂₅ and C₃₀ Highly Branched Isoprenoid Alkenes in The Branched and Cyclic Hydrocarbon Fractions of Qinghai Lake Sediments

1 Lanzhou Institute of Geology, Academia Sinica, Lanzhou 730000 China;
2 University of Oklahoma, School of Geology and Geophysics, Norman, OK 73019 USA

摘要

摘要: 在青海湖不同盐度的四孔近代沉积物岩芯（Ｑ－１６Ａ，ＱＨ，ＱＥ和ＱＧ）（图１）抽提物支链和环烷烃组分中检出了非常丰富的Ｃ₂₀，Ｃ₂₅和Ｃ₃₀高度支链类异戊二烯烯烃（ｈｉｇｈｌｙｂｒａｎｃｈｅｄｉｓｏｐｒｅｎｏｉｄａｌｋｅｎｅｓ），简称ＨＢＩ烯烃。这是在我国近代湖泊沉积物发现这类化合物的首次详细报导。由于Ｃ₂₀，Ｃ₂₅和Ｃ₃₀ＨＢＩ烯烃比正构烷烃具有较强的抵抗生物降解的能力（ＲｏｂｓｏｎａｎｄＲｏｗｌａｎｄ，１９８８ｂ），因此，它们广泛分布于各种近代环境中，如湖泊、海洋和高盐环境的近代沉积物中（ＲｏｗｌａｎｄａｎｄＲｏｂｓｏｎ，１９９０）。并且，具有１～６个双键的Ｃ₂₀，Ｃ₂₅和Ｃ₃₀烯烃经常是现代沉积物中丰富的烃类。最近在印度洋现代沉积物中又发现了一个新的具有７个双键的Ｃ₃₅ＨＢＩ烯烃（Ｈｏｅｆｓｅｔａｌ，１９９５）。全饱和的Ｃ₂₀（Ｉ，附图）、Ｃ₂₅（Ⅱ，附图）和Ｃ₃₀（Ⅲ，附图）ＨＢＩ烷烃已通过标样的合成确切地确定了它们的结构。在青海湖ＱＧ孔（尕海，咸水）和ＱＥ孔（耳海，淡水）抽提物中发现了Ｃ₂₀单烯（１号峰，图２ａ）。Ｃ₂₅烯烃（２号峰，图２ａ、２ｂ）和Ｃ₃₀烯烃（主要是３号和８号峰，图２ａ、２ｂ）存在于所有四孔沉积物中。
- 高度支链类异戊二烯烯烃（HBI烯烃） /
- 高度支链类异戊二烯噻吩（HBI噻吩） /
- 硅藻 /
- 石油成因
Abstract: The very abundant highly branched isoprenoid (HBI) alkenes (C₂₀,C₂₅ and C₃₀) have been detected in four cores of Qinghai Lake recent sediments. This is the first report of these compounds in Chinese recent lake sediments. Diatoms may be the biological source of these sedimentary HBI alkenes.
- BHI alkenes /
- HBI thiophenes /
- diatoms /
- petroleum origin

HTML全文

参考文献(1)

[1]

1.Barrick R. C.，Hedges J. I. and Peterson M. L.(1980) Hydrocarbon geochemistry of the Puget Sound region-I.Sedimentary acydic hydrocarbons. Geochim. Cosmochim. Acta 44. 1349-1362.

2.Barrick R. C. and Hedges J. I. (1981) Hydrocarbon geochemistry of the Puget Sound region-1 .Sedimentary diter-penoid, steroid and triterpenoid hydrocarbons. Geochim. Cosmochirn. Acta 45. 381-392.

3.Belt S. T.，Cooke D. A.，Hird S. J. and Rowland S. (1994) Structural Determination of a highly branched Czs sedi-mentary isoprenoid biomarker by NMR spectroscopy and Mass spectrometry. J. ChPm. Snc.，Chem. Commurz. 2077-2078.

4.Cranwell P..A. (1982) Lipids of aquatic sediments and sedimentary particulates. Prog. Lipid Res. 21,271-308.

5.Hird S. J.，Evans R. and Rowland S. J. (1992) Isolation and characterization of sedimentary and synthetic highlybranched C₂₀and C₂₅ monoenes. Mar. Chem. 37,117-129.

6.Hoefs M. J. L.，Sinninghe Damste J. S. and de Leeuw J. W. (1995) A novel Cas highly branched isoprenoid polyene in recent Indian (kean sediments. prg Geochem. 23, 263-267.

7.Kohnen M, E. L.，Sinninghe Damste J. S.，Rullkotter J.，ten Haven H. L. and de Leeuw J. W. (1990) Origin and transformation of C₂₅ and C₃₀ highly branched isoprenoid sulphur compounds, further evidence for the formation of or-ganically bound sulphur during early diagenesis. Gexhim. Cosrnochim. Acta 54,3053-3063.

8.Nichols P. D.，Volkman J. K.，Palmisane A. C.，Smith G. A. and White D. C.(1988) Occurrence of an isoprenoid C₂₅ diunsaturated alkene and high neutral lipid content in Antarctic sea-ice diatom communities. J. Phycol. 24, 90-96.

9.Requejo A. G. and Quinn J. G. (1983) Geochemistry of C₂₅ and C₃₀ biogenic alkenes in sediments of the Narragansett Bay estuary. Geochim. Cosmochim. Acta 47, 1075-1090.

10.Requejo A. G.，Quinn J. G.，Gearing J. N. and Gearing P. J. (1984) C₂₅ and C₃₀ biogenic alkenes in a sediment core from the upper anoxic basin of the Pettaquamscutt River (Rhode Island, U. S. A.).Org. Geochem. 7.1-10.

11.Robson J. N. and Rowland S. J. (1986 ) Indentification of novel widely distributed sedimentary acycGc sesterter-penoids. Nazure 324. 561-563.

12.Robson J. N. and Rowland S. J.(1988a) Synthesis of a highly branched Csosedimentary hydrocarbon. Tetrahedron Lett. 29, 3837-3840.

13.Robson J. N. and Rowland S. J. (19886) Biodegradation of highly branched isoporenoid hydrocarbons; A possible ex-planation of sedimentary abundance. In Aduances in Ch}ganic Geochemistry 1987, Chog. Georhern. 13. 691-695.

14.Rowland S. J.，Yon D. A.，Lewis C. A. and Maxwell J. R. (1985 ) Ocurrence of 2. 6. 10-trimethyl-7(3-methylbutyl)-dodecane and related hydrocarbons in the green alga Enteromorpha prolifera and sediments. Org.Geochem. 8, 207-213.

15.Rowland S. J. and Robson. J. N. (1990) The widespread occurrence of highly branched acyclic C₂₀. C₂₅and C₃₀ hy-drocarbons in recent sediments and biota-a review. Mar. Erruvon. Res. 30.191-216.

16.Sinninghe Damste J. S.，Van Koert E. R.，Kock-van Dalen A. C.，de leeuw J. W. and Schenck P. A. (1989) Char-acteri7ation of highly branched isoprenoid thiophenes occurring in sediments and immature crude oils. Org. Geochem.

17.Sinninghe Damste J. S. and Rijpstra W. I. C. (1993) Identification of a novel C₂₅ highly branched isoprenoid thiophenein sediments. Org. Geochcm. 20, 327-331.

18.Volkman J. K.，Barrett S. M. and Dunstan G. A. (1994 ) C₂₅and C₃₀branched isoprenoid alkenes in laboratorycultures of two marine diatoms. (kg. Geochem. 21，407-413.

19.Yon D. A.，Ryback G. and Maxwell J. R. (1982) 2. 6. 10-Trimethyl-7(3-methylbutyl) dodecane. a novelsedi-mentary biological marker compound, Tetrnhedrrm L.ett. 23, 2143-2146.

20.Yruela I.，Barbe A. and Grimalt J. O. (1990) Determination of double bond position and geometry in Linear andhighly branched hydrocarbons and fatty acids from gas chromatography-mass spectrometry of epoxides and diols gen-erated by stereospecific resin hydration. J. Chrnmmtoqr. Sci. 28. 421-427.

[1]	梁茹, 苏中堂, 马慧, 方继瑶, 林良彪. 川西地区中二叠统栖霞组白云岩成因分析 . 沉积学报, 2021, 39(6): 1506-1516. doi: 10.14027/j.issn.1000-0550.2021.074
[2]	惠荣耀, 丁安娜. 微生物在石油生成中的作用(二)——氢代谢及多源输入 . 沉积学报, 2018, 36(5): 1023-1031. doi: 10.14027/j.issn.1000-0550.2018.071
[3]	杨程宇, 李美俊, 倪智勇, 杨福林, 陈昊卫. 塔里木盆地西北缘玉尔吐斯组硅质岩成因及石油地质意义 . 沉积学报, 2016, 34(4): 653-661. doi: 10.14027/j.cnki.cjxb.2016.04.005
[4]	. 渤海湾西北岸埋藏牡蛎礁礁顶上下沉积物中硅藻对“礁泥转换”古沉积环境的重建 . 沉积学报, 2012, 30(5): 879-890.
[5]	霍秋立. 松辽盆地北部晚白垩系青一段源岩中芳基类异戊二烯烃的检出及意义 . 沉积学报, 2010, 28(4): 815-820.
[6]	王智慧. 石灰华扇(Tufa Fan)沉积物中的微型生物多样性 . 沉积学报, 2008, 26(4): 670-675.
[7]	王万春, 陶明信, 张小军, 任军虎. 李雅庄煤矿煤岩中C₂₅、C₃₀等无环类异戊二烯烷烃的检出及其地球化学意义 . 沉积学报, 2006, (6): 897-900.
[8]	王万春陶明信张小军任军虎. 李雅庄煤矿煤岩中C₂₅、C₃₀等无环类异戊二烯烷烃的检出及其地球化学意义 . 沉积学报, 2006, 24(06): 897-900.
[9]	李景贵, 郑建京, 刘文汇, 陈国俊, 孟自芳. 塔北、塔中地区碳酸盐岩及其原油中的二苯并噻吩类化合物 . 沉积学报, 2004, 22(2): 348-353.
[10]	覃文圣, 刘建波, 韩宝福, 王宪曾, 李福昌. 山东山旺中新世硅藻土的纹层类型及成因 . 沉积学报, 2004, 22(2): 267-275.
[11]	史基安, 邓津辉, 曾凡刚, 王琪. 石油二次运移物理模拟及运移特征分析 . 沉积学报, 2002, 20(2): 333-338.
[12]	王开发, 支崇远, 郑玉龙, 王洪根. 东海陆缘(闽北段)晚第四纪沉积的硅藻学研究 . 沉积学报, 2002, 20(1): 136-143.
[13]	卢鸿, 柴平霞, 孙永革, 彭平安. 轮南14井原油正构烷烃和类异戊二烯单体碳同位素研究 . 沉积学报, 2002, 20(3): 477-504.
[14]	李景贵. 海相碳酸盐岩二苯并噻吩类化合物成熟度参数研究进展与展望 . 沉积学报, 2000, 18(3): 480-483.
[15]	夏燕青, 孟仟祥, 王红勇, 杜丽, 王春江. 苯并噻吩系列化合物的成因模拟及其地球化学意义 . 沉积学报, 1999, 17(1): 127-129.
[16]	李振西, 范璞, 李景贵, 曾凡刚. 芳基类异戊二烯生标在指相上的应用 . 沉积学报, 1998, 16(2): 9-13.
[17]	谢晓安, 王仁德, 李光文, 卢华复. 塔里木盆地满加尔南切割谷的成因探讨与石油地质意义浅析 . 沉积学报, 1996, 14(2): 41-46.
[18]	吴治君, 罗斌杰, 王有孝, 王春江, 孟仟祥, 李玉兰. 塔里木盆地原油中二苯并噻吩的分布及主力油源岩类型判识 . 沉积学报, 1995, 13(3): 98-106.
[19]	张健, 盛国英, 傅家谟, B.R.T.Simoneit. 低对流层中不同高度大气尘埃类脂质的特征 . 沉积学报, 1991, 9(S1): 187-196.
[20]	王开发, 蒋辉. 黄海晚更新世以来的硅藻组合及其沉积环境 . 沉积学报, 1987, 5(1): 94-103.

施引文献

资源附件(0)

访问统计

点击查看大图

计量

文章访问数: 560
HTML全文浏览量: 22
PDF下载量: 311
被引次数: 0

姓名
邮箱
手机号码
标题
留言内容
验证码

留言板

青海湖沉积物支链和环烷烃组分中C₂₀，C₂₅和C₃₀高度支链类异戊二烯烯烃

作者简介:
李景贵,52岁,副研究员,有机地球化学

计量

C₂₀, C₂₅ and C₃₀ Highly Branched Isoprenoid Alkenes in The Branched and Cyclic Hydrocarbon Fractions of Qinghai Lake Sediments

计量

目录

青海湖沉积物支链和环烷烃组分中C₂₀，C₂₅和C₃₀高度支链类异戊二烯烯烃

1 中国科学院兰州地质研究所兰州 730000;

2 University of Oklahoma, School of Geology and Geophysics, Norman, OK 73019 USA

作者简介:
李景贵,52岁,副研究员,有机地球化学

English Abstract

C₂₀, C₂₅ and C₃₀ Highly Branched Isoprenoid Alkenes in The Branched and Cyclic Hydrocarbon Fractions of Qinghai Lake Sediments

1 Lanzhou Institute of Geology, Academia Sinica, Lanzhou 730000 China;

2 University of Oklahoma, School of Geology and Geophysics, Norman, OK 73019 USA

全文HTML

目录

友情链接

期刊在线

联系我们

留言板