C20, C25 and C30 Highly Branched Isoprenoid Alkenes in The Branched and Cyclic Hydrocarbon Fractions of Qinghai Lake Sediments
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摘要: 在青海湖不同盐度的四孔近代沉积物岩芯(Q-16A,QH,QE和QG)(图1)抽提物支链和环烷烃组分中检出了非常丰富的C20,C25和C30高度支链类异戊二烯烯烃(highlybranchedisoprenoidalkenes),简称HBI烯烃。这是在我国近代湖泊沉积物发现这类化合物的首次详细报导。由于C20,C25和C30HBI烯烃比正构烷烃具有较强的抵抗生物降解的能力(RobsonandRowland,1988b),因此,它们广泛分布于各种近代环境中,如湖泊、海洋和高盐环境的近代沉积物中(RowlandandRobson,1990)。并且,具有1~6个双键的C20,C25和C30烯烃经常是现代沉积物中丰富的烃类。最近在印度洋现代沉积物中又发现了一个新的具有7个双键的C35HBI烯烃(Hoefsetal,1995)。全饱和的C20(I,附图)、C25(Ⅱ,附图)和C30(Ⅲ,附图)HBI烷烃已通过标样的合成确切地确定了它们的结构。在青海湖QG孔(尕海,咸水)和QE孔(耳海,淡水)抽提物中发现了C20单烯(1号峰,图2a)。C25烯烃(2号峰,图2a、2b)和C30烯烃(主要是3号和8号峰,图2a、2b)存在于所有四孔沉积物中。
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关键词:
- 高度支链类异戊二烯烯烃(HBI烯烃) /
- 高度支链类异戊二烯噻吩(HBI噻吩) /
- 硅藻 /
- 石油成因
Abstract: The very abundant highly branched isoprenoid (HBI) alkenes (C20,C25 and C30) have been detected in four cores of Qinghai Lake recent sediments. This is the first report of these compounds in Chinese recent lake sediments. Diatoms may be the biological source of these sedimentary HBI alkenes.-
Key words:
- BHI alkenes /
- HBI thiophenes /
- diatoms /
- petroleum origin
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