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珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定

张水昌 龚再升 梁狄刚 吴克强 汪建蓉 宋孚庆 王培荣 王汇彤 何忠华

张水昌, 龚再升, 梁狄刚, 吴克强, 汪建蓉, 宋孚庆, 王培荣, 王汇彤, 何忠华. 珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定[J]. 沉积学报, 2004, 22(S1): 15-26.
引用本文: 张水昌, 龚再升, 梁狄刚, 吴克强, 汪建蓉, 宋孚庆, 王培荣, 王汇彤, 何忠华. 珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定[J]. 沉积学报, 2004, 22(S1): 15-26.
ZHANG Shui-chang, GONG Zai-sheng, LIANG Di-gang, WU Ke qiang, WANG Jian-rong, SONG Fu-qing, WANG Pei-rong, WANG Hui-tong, HE Zhong-hua. Geochemistry of Petroleum Systems in the Eastern Pearl River Mouth Basin-I:Oil Family Classification, Oil-source Correlation and Mixed Oil Analysis[J]. Acta Sedimentologica Sinica, 2004, 22(S1): 15-26.
Citation: ZHANG Shui-chang, GONG Zai-sheng, LIANG Di-gang, WU Ke qiang, WANG Jian-rong, SONG Fu-qing, WANG Pei-rong, WANG Hui-tong, HE Zhong-hua. Geochemistry of Petroleum Systems in the Eastern Pearl River Mouth Basin-I:Oil Family Classification, Oil-source Correlation and Mixed Oil Analysis[J]. Acta Sedimentologica Sinica, 2004, 22(S1): 15-26.

珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定

详细信息
    作者简介:

    张水昌,男,1961年出生教授级高级工程师油气地球化学研究

  • 中图分类号: P593

Geochemistry of Petroleum Systems in the Eastern Pearl River Mouth Basin-I:Oil Family Classification, Oil-source Correlation and Mixed Oil Analysis

  • 摘要: 对珠江口盆地东部原油和烃源岩抽提物进行了详细的生物标志化合物检测,结果发现存在两类不同特征的原油,第一类原油含有丰富的C304-甲基甾烷,而C19三环萜烷、双杜松烷(主要是T构型)等代表陆生高等植物生源的分子化合物浓度低,与典型湖相沉积的文昌组烃源岩有良好的可比性;另一类原油具有高丰度的双杜松烷和C19三环萜烷以及较高的Pr/Ph值等,代表着偏氧化环境下以高等植物生源为主的恩平组湖沼相烃源岩的贡献,但这类原油中同时也不同程度地含有只是在文昌组岩石中才有的C304-甲基甾烷,因而认为这类油是两套烃源岩的混源产物,恩平组原油的混合比例最高可达80%以上,主要分布在惠州凹陷及其南边的西惠地凸起上。原油配比实验表明,即使在文昌组生成的原油中加入50%-80%的恩平组原油,混合油仍表现出文昌组生源的特征。因此,4-甲基甾烷的存在不能作为判识珠江口盆地东部油源主要是文昌组的唯一证据。文昌组烃源岩对珠-坳陷商业性油藏的贡献是普遍的,但恩平组烃源岩对惠州凹陷周边凸起上的油田/油藏的显著贡献不容忽视。正是由于恩平组生成的原油的再次注入,使得早期发生生物降解了的油藏再次充满,使油质变轻。
  • [1] Li M, Larter S R, Mei B, et al. Maturity assessment of immature oils produced from the Shahejie Formation of the Liaohe Basin, NE China . In: Grimalt J O, Dorronsoro C. Eds. Organic Geochemistry: Developments and App lications to Energy, Climate, Environment. 1995
    [2] Li M, Larter S R, Lin R, et al. Resolution of immature oil paradoxe s in the block-faulting basins: a successful exploration case in eastern China. In: European Association of Organic Geochemists(eds). Abstracts of the 19 th International Meeting on Organic Geochemistry. TUBITAK Mamara Research C enter, Istanbul, 1999. 123~124
    [3] Li S, Pang X, Li M, et al. Petroleum systems in the Bohai Bay Basin : Part 1. Distribution and organic geochemistry of petroleum source rocks in the Niuzhuang South Slope. Organic Geochemistry, 2003, 34(3): 389~412
    [4] 王文军,宋宁,姜乃煌,等. 未熟油与成熟油的混源实验、混源理论图版及其应用. 石油勘探与开发,1999,26(4):34~37
    [5] 黎茂稳. 油气二次运移研究的基本思路和几个应用实例. 石油勘探与开发, 2000,27(4):11~19
    [6] Pang X, Li M, Li S, et al. Origin of crude oils in the Jinhu Depres sion of North Jiangsu-South Yellow Sea Basin, eastern China. Organic Geoch emistry, 2003, 34(4):553~574
    [7] Pang X, Li M, Li S, et al. Petroleum systems in the Bohai Bay Basin : Part 2. Geochemical evidence for significant contribution of mature source roc ks to immature oils in the Bamianhe field . Organic Geochemistry, 2003, 34( 7): 931~950
    [8] Curiale J A. Non-source rock origins for certain compound types in cru de oil. In: Landais P, ed. Abstracts of the 20th International Meeting on Organ ic Geochemistry. European Association of Organic Geochemists. Nancy, 2001. 158~ 159
    [9] Jiang C, Li M, Osadetz K G, et al. Bakken/Madison petroleum systems in the Canadian Williston Basin. Part 2: molecular markers diagnostic of Bakken and Lodgepole source rocks . Organic Geochemistry, 2001, 32: 1037~1054
    [10] Jiang C, Li M. Bakken/Madison petroleum systems in the Canadian Williston Ba sin. Part 3: Geochemical evidence for significant contribution of Bakken-derive d oils in Madison Group reservoirs. Organic Geochemistry, 2002, 33: 761~78 7
    [11] Jiang C, Li M. Bakken/Madison petroleum systems in the Canadian Williston Ba sin. Part 4: Diphenylmethanes and benzylcyclohexanes as indicators for oils deri ved from the Madison petroleum system . Organic Geochemistry, 2002, 33: 855 ~860
    [12] Peters K E, Moldowan J M, Driscole A R, et al. Origin of Beatrice oil by co-sourcing from Devonian and Middle Jurassic source rocks, Inner Moray Firth, United Kingdom. American Association of Petroleum Geologisits Bulletin, 1989, 7 3: 454~471
    [13] Bissada A. Geochemistry offers new E & P tools. The American Oil & Gas Repor ter, 1996, 10: 83~88
    [14] Horstad I, Larter S R. Petroleum migration, alteration, and remigration with in Troll Field, Norwegian.1997
    [15] Santos Neto E V, Hayes J M. Use of hydrogen and carbon stable isotopes chara cterizing oils from the Potiguar Basin (Onshore), northeastern Brazil. Bull etin of the American Association of Petroleum Geologists, 1999, 83: 496~518
    [16] Li M, Huang Y, Obermajer M, et al. Hydrogen isotopic compositions of ind ividual alkanes as a new approach to petroleum correlation: case studies from th e Western Canada Sedimentary Basin. Organic Geochemistry, 2001, 32: 1387~1 399
    [17] Chen J, Deng C, Liang D, et al. Mixed oils derived from multiple source rocks in the Cainan oil field, Junggar Basin, Northwest China. Part II: artifici al mixing experiments on typical crude oils and quantitative oil-source correla tion. Organic Chemistry, 2003, 34(7): 911~930
    [18] 陈斯忠,张明辉,张俊达. 珠江口盆地东部油气生成与勘探. 石油与天然气地质 ,1991, 12(2): 95~106
    [19] 赵柳生,李传宇,梁安耀,等. 珠江口盆地. 翟光明等. 中国石油地质志·卷十六(下). 北京: 石油工业出版社,1992.77~340
    [20] 黄第藩,李晋超. 中国陆相盆地干酪根类型划分的X图解. 地球化学,1982, 11(1 ): 21~30
    [21] Alexander R, Kagi R I, Volkman J K, et al. The geochemistry of some biod egraded Australian oils. Australian Petroleum Exploration Association Journ al, 1983, 23(1): 53~63
    [22] Volkman J K. Biological marker compounds as indicators of the depositional e nvironments of petroleum source rocks. In: Fleet A J, Kelts K, Talbot M R, eds. Lacustrine Petroleum Source Rocks. Special Publication No. 40. Geological Soci ety, London, 1988.103~122
    [23] van Aarssen B G K, de Leeuw J W. On the identification and occurrence of oli gomerized sesquiterpenoid compounds in oils and sediments of southeast Asia . Abstracts of the 14th International Meeting on Organic Geochemistry, Paris, Se ptember, 1989. 18~22
    [24] van Aarssen B G K, Cox H C, Hoogendoorn P, et al. A cadinene bioploymer present in fossil and extant Dammar resins as source for cadinanes and dicadinan es in crude oils from South East Asia. Geochimica et Cosmochimica Acta, 199 0, 54: 3021~3031
    [25] 张泉兴,张启明. 莺-琼盆地梅山组海相烃源岩的树脂化合物.中国海洋石油西部公司勘探开发科学研究院. 莺歌海盆地石油地质论文集. 北京: 地震出版社,1993.1 8~26
    [26] Ourisson G, Albrecht P, Rohmer M. Predictive microbial biochemistry from mol ecular fossils to procaryotic membrances. Trends in Biochemical Science, 19 82, 7: 236~239
    [27] Connan J, Restle A, Albrecht P. Biodegradation of crude oil in the Aquitaine basin. Physics and Chemistry of the Earth, 1980, 12: 1~17
    [28] Aquino Neto F R, Trendel J M, Restle A, et al. Occurrence and formation of tricyclic and tetracyclic terpanes in sediments and petroleums. In: Bj orΦy M, et al. eds. Advances in Organic Geochemistry 1981. J Wiley an d Sons, New York, 1983.659~676
    [29] Peters K E, Moldowan J M. The Biomarker Guide. Interpreting Molecular Fossil s in Petroleum and Ancient Sediments. Prentice Hall, Englewood Cliffs, NJ, 1993
    [30] Moldowan J M, Dahl J, Huizinga B J, et al. The molecular fossil record o f oleanane and its relation to angiosperms. Science, 1994, 265: 768~771
    [31] Ekweozor C M, Okogun J I, Ekong D E U, et al. Preliminary organic geoche mical studies of samples from the Niger Delta (Nigeria). Chemical Geology , 1979, 27: 29~37
    [32] Wolff G A, Lamb N A, Maxwell J R. The origin and fate of 4-methyl steroid h ydrocarbons I. 4-methyl steranes. Geochimica et Cosmochimica Acta, 1986, 5 0: 335~342
    [33] Volkman J K, Kearney P, Jeffrey S W. A new source of 4-methyl sterols and 5 a(H)-stanols in sediments: prymnesiophyte microalgae of the genus Pavlova. Organic Geochemistry, 1990, 15: 489~497
    [34] Fu J, Pei C, Sheng G., et al. A geochemical investigation of crude oils from eastern Pearl River mouth basin, South China. Journal of Southeast A sian Earth Sciences, 1992, 7: 271~272
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出版历程
  • 收稿日期:  2004-02-06
  • 刊出日期:  2004-12-10

目录

    珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定

      作者简介:

      张水昌,男,1961年出生教授级高级工程师油气地球化学研究

    • 中图分类号: P593

    摘要: 对珠江口盆地东部原油和烃源岩抽提物进行了详细的生物标志化合物检测,结果发现存在两类不同特征的原油,第一类原油含有丰富的C304-甲基甾烷,而C19三环萜烷、双杜松烷(主要是T构型)等代表陆生高等植物生源的分子化合物浓度低,与典型湖相沉积的文昌组烃源岩有良好的可比性;另一类原油具有高丰度的双杜松烷和C19三环萜烷以及较高的Pr/Ph值等,代表着偏氧化环境下以高等植物生源为主的恩平组湖沼相烃源岩的贡献,但这类原油中同时也不同程度地含有只是在文昌组岩石中才有的C304-甲基甾烷,因而认为这类油是两套烃源岩的混源产物,恩平组原油的混合比例最高可达80%以上,主要分布在惠州凹陷及其南边的西惠地凸起上。原油配比实验表明,即使在文昌组生成的原油中加入50%-80%的恩平组原油,混合油仍表现出文昌组生源的特征。因此,4-甲基甾烷的存在不能作为判识珠江口盆地东部油源主要是文昌组的唯一证据。文昌组烃源岩对珠-坳陷商业性油藏的贡献是普遍的,但恩平组烃源岩对惠州凹陷周边凸起上的油田/油藏的显著贡献不容忽视。正是由于恩平组生成的原油的再次注入,使得早期发生生物降解了的油藏再次充满,使油质变轻。

    English Abstract

    张水昌, 龚再升, 梁狄刚, 吴克强, 汪建蓉, 宋孚庆, 王培荣, 王汇彤, 何忠华. 珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定[J]. 沉积学报, 2004, 22(S1): 15-26.
    引用本文: 张水昌, 龚再升, 梁狄刚, 吴克强, 汪建蓉, 宋孚庆, 王培荣, 王汇彤, 何忠华. 珠江口盆地东部油气系统地球化学-Ⅰ:油组划分、油源对比及混源油确定[J]. 沉积学报, 2004, 22(S1): 15-26.
    ZHANG Shui-chang, GONG Zai-sheng, LIANG Di-gang, WU Ke qiang, WANG Jian-rong, SONG Fu-qing, WANG Pei-rong, WANG Hui-tong, HE Zhong-hua. Geochemistry of Petroleum Systems in the Eastern Pearl River Mouth Basin-I:Oil Family Classification, Oil-source Correlation and Mixed Oil Analysis[J]. Acta Sedimentologica Sinica, 2004, 22(S1): 15-26.
    Citation: ZHANG Shui-chang, GONG Zai-sheng, LIANG Di-gang, WU Ke qiang, WANG Jian-rong, SONG Fu-qing, WANG Pei-rong, WANG Hui-tong, HE Zhong-hua. Geochemistry of Petroleum Systems in the Eastern Pearl River Mouth Basin-I:Oil Family Classification, Oil-source Correlation and Mixed Oil Analysis[J]. Acta Sedimentologica Sinica, 2004, 22(S1): 15-26.
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