广西百色盆地干酪根的研究&mdash;&mdash;兼探干酪根的演化与粘土矿物的关系

陆琦; 刘惠芳; 罗莉绢; 雷新荣

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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

陆琦, 刘惠芳, 罗莉绢, 雷新荣

文章导航 > 沉积学报 > 1993 > 11(2): 124-132

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

引用本文:

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

Lu Qi, Liu Huifang, Luo Lijuan, Lei Xinrong. Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals[J]. Acta Sedimentologica Sinica, 1993, 11(2): 124-132.

Citation:

Lu Qi, Liu Huifang, Luo Lijuan, Lei Xinrong. Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals[J]. Acta Sedimentologica Sinica, 1993, 11(2): 124-132.

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

引用本文:

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

Citation:

广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

中国地质大学, 武汉

基金项目: 国家自然科学基金资金,编号 4880082

详细信息

作者简介:
陆琦,男,52岁,教授,粘土矿物.

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文章访问数: 515
HTML全文浏览量: 3
PDF下载量: 379
被引次数: 0

Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

China University of Geosciences, Wuhan

摘要

摘要: 本文用X射线、微区分析等方法对广西百色盆地那读三段泥岩中的干酪根进行了详细研究,该盆地干酪根的芳香度（Fa）为0.28至0.37,芳香核厚度（Le）为16.60A到20.76A,芳香片层数（n）为5到6层,证明属Ⅱ型干酪根,在同一剖面,fa随深度增加而变大,表明了干酪根向成熟方向转化。在干酪根中碳元素的分布是不均匀的,一般中间含量高,向边部则含量变低,铁及硅元素也向中间聚集,多数情况下形成FeS₂核,在核的周围分布有粘土矿物。干酪根成熟程度的变化趋势与粘土矿物的演化趋势在宏观上是一致的,即与蒙脱石转化为伊/蒙混层粘土矿物的趋势一致。并从化学健和能量方面对这种过程进行了一些探讨。
- 干酪根 /
- 百色盆地 /
- 伊/蒙混层 /
- 芳香度
Abstract: Kerogen is the direct original material of oil-forming. To determine the type and the mature degree of kerogen is one of the important work in petroleum geology. While studing the clay minerals of Baise Basin,Guangxi,the authors made some detialed work on the kerogen of this oil-forming region. The type,mature degree,and the evolution process of kerogen was determined through X-ray diffraction and micro-region analysis method,and also by microscopic,atom distribution and infrared work. According to the results of X-ray analysis, the aliphatic degree (Fa) of the kerogen in this region is 0. 28 to 0. 37. On increasing of the depth in the same geological section,the Fa becomes higher, that is, the kerogen evoluted to mature. By calculation, the height of aliphatic nuclei (Lc) is between 16. 60 and 20. 76 A,the layer number (n) of them is 5 to 6. These are the characteristics of type III kerogen. The evolution process of the kerogen in this region was studied using micro-region method,and also using some routine methods. The lower matured kerogen was photoed by microscope, and the distribution of the atoms in it was analyzed by electronic probe. It is shown that the carbon atom in this kind of lower mature kerogen is not homogeneous,normally higher in the center,lower in the outer part. Iron and silica are also concentrated to the center. Most of the Kerogen have FeS2 nuclei,and around the nuclei mainly are clay minerals. The evolution trent of the mature degree of the kerogen is consistent with the evolution trend of the clay minerals,that is,montmorillonite evoluted to illite/montmorillonite. The combining patterns of organic molecules and clay minerals were also discussed. According to the thermodynamics data and some experiments of transforming clay minerals, we qualitatively calculated the water and heat that produced by the montmorillonite to illite. It will let out 30 to 40 grams of water and 100 kcal of heat by 1 mol montmorillonite transform to illite. This may be the medium and dynamic power source of the forming,evolution,and decomposition of kerogen. It is concluded that the clay minerals were the catalytic promoter for organic material evelute to hydrocarbon.

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参考文献(7)

[1]	中国科学院贵阳地球化学研究所，1981，铁的地球化学，科学出版社。
[2]	陆琦，雷新荣，刘惠芳，1991，不规则伊/蒙混层粘土矿物的成因类型及晶体化学分类，矿物学报，11卷，2期，97~104页.
[3]	林伟山，白正华，张哲，1985，矿物及有关化合物热力学数据手册，科学出版社。
[4]	秦匡宗，张秀义，劳永新，1987，干酩根的X射线研究，沉积学报，5卷，1期，26~35页。
[5]	黄第藩，1984.陆相有机质演化和成烃机理，石油出版社.
[6]	Brindley G. W. and Brown G.,1984,Crystal Structure of Clay Minerals and Their X-ray Identification，London Press p. 197~247
[7]	Yen T. F. Erdman J. G.，and Pollack S. S.，1961，Analytical Chemistry，V. 33, N. 11，p. 1587~1594.

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[2]	侯孝欢, 吴应琴, 王作栋, 刘艳红. 绿河页岩干酪根分步瞬时热解演化特征及机理研究 . 沉积学报, 2018, 36(3): 630-638. doi: 10.14027/j.issn.1000-0550.2018.083
[3]	朱扬明, 李颖, 郝芳, 邹华耀, 郭旭升. 四川盆地海、陆相烃源岩有机质稳定碳同位素组成变化及其地球化学意义 . 沉积学报, 2017, 35(6): 1254-1264. doi: 10.14027/j.cnki.cjxb.2017.06.016
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[5]	王涌泉. 干酪根化学降解产物的碳同位素组成研究 . 沉积学报, 2007, 25(5): 778-781.
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[11]	王万春, 徐永昌, Manfred Schidlowski, Eckhard Faber, Wolfgang Stahl. 不同沉积环境及成熟度干酪根的碳氢同位素地球化学特征 . 沉积学报, 1997, 15(S1): 132-137.
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[13]	王万春. 天然气、原油、干酪根的氢同位素地球化学特征 . 沉积学报, 1996, 14(S1): 131-135.
[14]	刘洛夫, 王伟华, 李术元. 干酪根二次生烃热模拟实验研究 . 沉积学报, 1995, 13(S1): 147-150.
[15]	张柏生, 刘文汇, 徐永昌, 王兆云, 吴铁生. 辽河盆地过渡带有机地球化学（Ⅰ）──不同赋存状态的有机质与过渡带气的形成 . 沉积学报, 1994, 12(4): 58-65.
[16]	周炎如. 应用显微FT—IR光谱技术“原位”研究沉积岩中生油母质──干酪根 . 沉积学报, 1994, 12(4): 22-30.
[17]	陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究──兼探干酪根的演化与粘土矿物的关系 . 沉积学报, 1994, 12(4): 31-39.
[18]	秦匡宗, 吴肖令. 高磁场固态碳13核磁共振法研究干酪根的热降解成烃机理 . 沉积学报, 1990, 8(1): 19-27.
[19]	王铮. 干酪根的赋存状态与成熟度的关系 . 沉积学报, 1990, 8(4): 124-129.
[20]	秦匡宗, 张秀义, 劳永新. 干酪根的X射线衍射研究 . 沉积学报, 1987, 5(1): 26-36.

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文章访问数: 515
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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

中国地质大学, 武汉

基金项目: 国家自然科学基金资金,编号 4880082

作者简介:
陆琦,男,52岁,教授,粘土矿物.

收稿日期: 1991-07-24
刊出日期: 1993-06-10

关键词:

干酪根 /

百色盆地 /

伊/蒙混层 /

芳香度

摘要: 本文用X射线、微区分析等方法对广西百色盆地那读三段泥岩中的干酪根进行了详细研究,该盆地干酪根的芳香度（Fa）为0.28至0.37,芳香核厚度（Le）为16.60A到20.76A,芳香片层数（n）为5到6层,证明属Ⅱ型干酪根,在同一剖面,fa随深度增加而变大,表明了干酪根向成熟方向转化。在干酪根中碳元素的分布是不均匀的,一般中间含量高,向边部则含量变低,铁及硅元素也向中间聚集,多数情况下形成FeS₂核,在核的周围分布有粘土矿物。干酪根成熟程度的变化趋势与粘土矿物的演化趋势在宏观上是一致的,即与蒙脱石转化为伊/蒙混层粘土矿物的趋势一致。并从化学健和能量方面对这种过程进行了一些探讨。

English Abstract

Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

China University of Geosciences, Wuhan

Received Date: 1991-07-24
Publish Date: 1993-06-10

Abstract: Kerogen is the direct original material of oil-forming. To determine the type and the mature degree of kerogen is one of the important work in petroleum geology. While studing the clay minerals of Baise Basin,Guangxi,the authors made some detialed work on the kerogen of this oil-forming region. The type,mature degree,and the evolution process of kerogen was determined through X-ray diffraction and micro-region analysis method,and also by microscopic,atom distribution and infrared work. According to the results of X-ray analysis, the aliphatic degree (Fa) of the kerogen in this region is 0. 28 to 0. 37. On increasing of the depth in the same geological section,the Fa becomes higher, that is, the kerogen evoluted to mature. By calculation, the height of aliphatic nuclei (Lc) is between 16. 60 and 20. 76 A,the layer number (n) of them is 5 to 6. These are the characteristics of type III kerogen. The evolution process of the kerogen in this region was studied using micro-region method,and also using some routine methods. The lower matured kerogen was photoed by microscope, and the distribution of the atoms in it was analyzed by electronic probe. It is shown that the carbon atom in this kind of lower mature kerogen is not homogeneous,normally higher in the center,lower in the outer part. Iron and silica are also concentrated to the center. Most of the Kerogen have FeS2 nuclei,and around the nuclei mainly are clay minerals. The evolution trent of the mature degree of the kerogen is consistent with the evolution trend of the clay minerals,that is,montmorillonite evoluted to illite/montmorillonite. The combining patterns of organic molecules and clay minerals were also discussed. According to the thermodynamics data and some experiments of transforming clay minerals, we qualitatively calculated the water and heat that produced by the montmorillonite to illite. It will let out 30 to 40 grams of water and 100 kcal of heat by 1 mol montmorillonite transform to illite. This may be the medium and dynamic power source of the forming,evolution,and decomposition of kerogen. It is concluded that the clay minerals were the catalytic promoter for organic material evelute to hydrocarbon.

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

引用本文:

陆琦, 刘惠芳, 罗莉绢, 雷新荣. 广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系[J]. 沉积学报, 1993, 11(2): 124-132.

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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

作者简介:
陆琦,男,52岁,教授,粘土矿物.

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Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

中国地质大学, 武汉

作者简介:
陆琦,男,52岁,教授,粘土矿物.

English Abstract

Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

China University of Geosciences, Wuhan

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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

作者简介: 陆琦,男,52岁,教授,粘土矿物.

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Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

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广西百色盆地干酪根的研究——兼探干酪根的演化与粘土矿物的关系

中国地质大学, 武汉

作者简介: 陆琦,男,52岁,教授,粘土矿物.

English Abstract

Studies of Kerogen From Baise Basin,Guangxi-Also on Relationship of Evolution of Kerogen and Clay Minerals

China University of Geosciences, Wuhan

全文HTML

目录

友情链接

期刊在线

联系我们

作者简介:
陆琦,男,52岁,教授,粘土矿物.

作者简介:
陆琦,男,52岁,教授,粘土矿物.