Analysis on Gallium Geochemical Characteristics and Ore-forming Environment of Bauxite Mine in Yinkuangyakou of Chongqing
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摘要: 通过对重庆银矿垭口铝土矿床的研究,发现该矿床中镓含量普遍超过了工业综合利用的最低指标,在含矿岩系中均有分布,且镓和Al2O3呈弱的正相关关系。通过Sr与Ba比值推断,矿床以陆相沉积为主,沉积过程中有海水的介入;样品Rb/K值小于标准海洋沉积值(0.006),属半咸水海陆过渡带沉积~淡水沉积;U/Th比值和V/Cr比值分别在0.1~0.73和0.5~2.04之间,由此可以判别含矿岩系属于典型氧化环境;对Ni/Co比值的计算发现含矿岩系可能在沉积过程中受到了海水的改造;Ga/Al比值变化范围主要在0.53~1.74,成矿介质酸碱度的变化幅度较小;从含矿岩系矿物组合中含黄铁矿、高岭石等矿物可以推断介质为酸性的可能性较大。稀土元素球粒陨石标准化分布模式表明,轻稀土富集,重稀土亏损,据样品统计,δCe<0.95为负异常的4个样品分布在探槽工程底部,0.95<δCe<1.05为正常的样品个数为3,其余19个为正异常,Eu显示为负异常;总体水介质应以淡水为主、基本处于氧化环境、弱酸性介质。因此该矿床是以陆相沉积、淡水作用为主的海陆交互环境。Abstract: Research on the Chongqing Yinkuangyakou bauxite deposit revealed that gallium is generally more than the lowest indicators of comprehensive utilization of industrial,gallium content of the bauxite deposits in the ore-bearing series are distributed, and gallium to Al2O3 weakly positive correlation. Sr/Ba ratio inferred continental sedimentation is main; the result which the sample Rb/K value is less than the standard marine sedimentary 0.006 reflected brackish transitional zone deposition to freshwater deposition; U/Th ratio range 0.1 to 0.73 and V/Cr ratio from 0.5 to 2.04, which can distinguish ore-bearing rock series are typical oxidizing environment; Seawater may influence ore-bearing rock series during deposition by the calculation of the ratio of Ni/Co found; Ga/Al ratio varied from 0.53 to 1.74, the mineralization medium pH changed magnitude smaller; containing pyrite from the ore-bearing rock mineral assemblage, kaolinite and other minerals can be inferred that the medium is acidic likely. Chondrite-normalized distribution patterns shows LREE enrichment and HREE losses, δCe <0.95 ( four samples )is negative anomalies, 0.95 <δCe <1.05 for normal samples 3, 19 positive anomalies,Eu shows negative anomalies; the overall aqueous media should mainly freshwater basic in oxidizing and acidic environment. The deposit is a continental deposit with the main freshwater to paralic environment.
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Key words:
- gallium /
- bauxite deposit /
- geochemistry /
- Ore-forming environment /
- Chongqing
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