爱沙尼亚油页岩富黏球形藻干酪根快速连续分步热解研究

敖添; 孟宪新; 卢鸿; 张志荣; 彭平安; 敖添; 孟宪新; 卢鸿; 张志荣; 彭平安

doi:10.14027/j.issn.1000-0550.2024.132

[1]

纪明候.1997.海藻化学[M]. 北京：科学出版社：1-777.

Ji Minghou. 1997. Seaweed chemistry[M]. Beijing: Science Press: 1-777.

[2]

梁狄刚，张水昌，张宝民，等. 2000. 从塔里木盆地看中国海相生油问题[J]. 地学前缘，7（4）：534-547.

Liang Digang, Zhang Shuichang, Zhang Baomin, et al. 2000. Understanding on marine oil generation in China based on Tarim Basin[J]. Earth Science Frontiers, (4): 534-547.

[3]

刘德汉，肖贤明，贾蓉芬，等. 2000. 碳酸盐岩生烃运移的激光—荧光和有机包裹体研究[J]. 海相油气地质，5（1/2）：62-68.

Liu Dehan, Xiao Xianming, Jia Rongfen, et al. 2000. Carbonate hydrocarbon migration of laser-the study of fluorescence and organic in clusions[J]. Marine Origin Petroleum Geology, 5(1/2): 62-68.

[4]

孙永革，茅晟懿，王飞宇，等. 2014. 塔里木盆地奥陶纪地层中Kukersite型生油岩的发现及其石油地质意义[J]. 科学通报，59（1）：72-79.

Sun Yongge, Mao Shengyi, Wang Feiyu, et al. 2014. Identification of the Kukersite-type source rocks in the Ordovician stratigraphy from the Tarim Basin, NW China[J]. Chinese Science Bulletin, 59(1): 72-79.

[5]

Bertheas O, Metzger P, Largeau C. 1999. A high molecular weight complex lipid, aliphatic polyaldehyde tetraterpenediol polyacetal from Botryococcus braunii (L race)[J]. Phytochemistry, 50(1): 85-96.

[6]

Blokker P, van Bergen P, Pancost R, et al. 2001. The chemical structure of Gloeocapsomorpha prisca microfossils: Implications for their origin[J]. Geochimica et Cosmochimica Acta, 65(6): 885-900.

[7]

da Silva T F, Mendonça Filho J G, da Silva M C, et al. 2016. Botryococcus braunii versus Gloecapsomorpha prisca: Chemical composition correlation using laser micropyrolysis-gas chromatography/mass spectrometer (LmPy-GCMSMS)[J]. International Journal of Coal Geology, 168: 71-79.

[8]

de Leeuw J W, Largeau C. 1993. A review of macromolecular organic compounds that comprise living organisms and their role in Kerogen, coal, and petroleum formation[M]//Engel M H, Macko S A. Organic geochemistry: Principles and applications. Boston, MA: Springer US: 23-72.

[9]

del Río J C, Gutiérrez A, Rodríguez I M, et al. 2007. Composition of non-woody plant lignins and cinnamic acids by Py-GC/MS, Py/TMAH and FT-IR[J]. Journal of Analytical and Applied Pyrolysis, 79(1/2): 39-46.

[10]

Delahais V, Metzger P. 1997. Four polymethylsqualene epoxides and one acyclic tetraterpene epoxide from Botryococcus braunii [J]. Phytochemistry, 44(4): 671-678.

[11]

Derenne S, Largeau C, Casadevall E, et al. 1990. Characterization of Estonian Kukersite by spectroscopy and pyrolysis: Evidence for abundant alkyl phenolic moieties in an Ordovician, marine, type II/I kerogen[J]. Organic Geochemistry, 16(4/5/6): 873-888.

[12]

Derenne S, Largeau C, Hetényi M, et al. 1997. Chemical structure of the organic matter in a Pliocene maar-type shale: Implicated Botryococcus race strains and formation pathways[J]. Geochimica et Cosmochimica Acta, 61(9): 1879-1889.

[13]

Derenne S, Largeau C, Landais P, et al. 1994. Spectroscopic features of Gloeocapsomorpha prisca colonies and of interstitial matrix in kukersite as revealed by transmission micro-FT-i.r.: Location of phenolic moieties[J]. Fuel, 73(4): 626-628.

[14]

Derenne S, Metzger P, Largeau C, et al. 1992. Similar morphological and chemical variations of Gloeocapsomorpha prisca in Ordovician sediments and cultured Botryococcus braunii as a response to changes in salinity[J]. Organic Geochemistry, 19(4/5/6): 299-313.

[15]

Dillon J G, Castenholz R W. 1999. Scytonemin, a cyanobacterial sheath pigment, protects against UVC radiation: Implications for early photosynthetic life[J]. Journal of Phycology, 35(4): 673-681.

[16]

Douglas A G, Damsté J S S, Fowler M G, et al. 1991. Unique distributions of hydrocarbons and sulphur compounds released by flash pyrolysis from the fossilised alga Gloeocapsomorpha prisca, a major constituent in one of four Ordovician kerogens[J]. Geochimica et Cosmochimica Acta, 55(1): 275-291.

[17]

Foster C B, Reed J D, Wicander R. 1989. Gloeocapsomorpha prisca ZALESSKY, 1917: A new study: Part I: Taxonomy, geochemistry, and paleoecology[J]. Geobios, 22(6): 735-759.

[18]

Fowler M G. 1992. The influence of Gloeocapsomorpha prisca on the organic geochemistry of oils and organic-rich rocks of Late Ordovician age from Canada[M]//Schidlowski M, Golubic S, Kimberley M M, et al. Early organic evolution: Implications for mineral and energy resources. Berlin, Heidelberg: Springer: 336-356.

[19]

Fowler M G, Douglas A G. 1984. Distribution and structure of hydrocarbons in four organic-rich Ordovician rocks[J]. Organic Geochemistry, 6: 105-114.

[20]

Fowler M G, Stasiuk L D, Hearn M, et al. 2004. Evidence for Gloeocapsomorpha prisca in Late Devonian source rocks from southern Alberta, Canada[J]. Organic Geochemistry, 35(4): 425-441.

[21]

Grice K, Schouten S, Peters K E, et al. 1998. Molecular isotopic characterisation of hydrocarbon biomarkers in Palaeocene-Eocene evaporitic, lacustrine source rocks from the Jianghan Basin, China[J]. Organic Geochemistry, 29(5/6/7): 1745-1764.

[22]

Hoffmann C F, Foster C B, Powell T G, et al. 1987. Hydrocarbon biomarkers from Ordovician sediments and the fossil alga Gloeocapsomorpha prisca Zalessky 1917[J]. Geochimica et Cosmochimica Acta, 51(10): 2681-2697.

[23]

Huang Y R, Han X X, Jiang X M. 2014. Comparison of fast pyrolysis characteristics of Huadian oil shales from different mines using Curie-point pyrolysis-GC/MS[J]. Fuel Processing Technology, 128: 456-460.

[24]

Johnson L M, Rezaee R, Smith G C, et al. 2020. Kinetics of hydro-carbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, western Australia[J]. International Journal of Coal Geology, 232: 103623.

[25]

Larter S R, Horsfield B. 1993. Determination of structural components of kerogens by the use of analytical pyrolysis methods [M]//Engel M H, Macko S A. Organic geochemistry: Principles and applications. Boston, MA: Springer US: 271-287.

[26]

Li T, Su J, Wang C, et al. 2022. Advances in the development and application of analytical pyrolysis in biomass research: A review[J]. Energy Conversion and Management, 271: 116302.

[27]

Lille Ü, Heinmaa I, Pehk T. 2003. Molecular model of Estonian kukersite kerogen evaluated by ¹³C MAS NMR spectra[J]. Fuel, 82(7): 799-804.

[28]

Metzger P, Casadevall E. 1992. Ether lipids from Botryococcus braunii and their biosynthesis[J]. Phytochemistry, 31(7): 2341-2349.

[29]

Metzger P, Largeau C. 1994. A new type of ether lipid comprising phenolic moieties in Botryococcus braunii. Chemical structure and abundance, and geochemical implications[J]. Organic Geochemistry, 22(3/4/5): 801-814.

[30]

Metzger P, Pouet Y, Bischoff R, et al. 1993. An aliphatic polyaldehyde from Botryococcus braunii (A race)[J]. Phytochemistry, 32(4): 875-883.

[31]

Nip M, de Leeuw J W, Crelling J C. 1992. Chemical structure of bituminous coal and its constituting maceral fractions as revealed by flash pyrolysis[J]. Energy & Fuels, 6(2): 125-136.

[32]

Reed J D, Illich H A, Horsfield B. 1986. Biochemical evolutionary significance of Ordovician oils and their sources[J]. Organic Geochemistry, 10(1/2/3): 347-358.

[33]

Riboulleau A, Derenne S, Largeau C, et al. 2001. Origin of contrasting features and preservation pathways in kerogens from the Kashpir oil shales (Upper Jurassic, Russian Platform)[J]. Organic Geochemistry, 32(5): 647-665.

[34]

Saiz-jimenez C, Boon J J, Hedges J I, et al. 1987. Chemical characterization of recent and buried woods by analytical pyrolysis: Comparison of pyrolysis data with ¹³C NMR and wet chemical data[J]. Journal of Analytical and Applied Pyrolysis, 11: 437-450.

[35]

Senftle J T, Larter S R, Bromley B W, et al. 1986. Quantitative chemical characterization of vitrinite concentrates using pyrolysis-gas chromatography. Rank variation of pyrolysis products[J]. Organic Geochemistry, 9(6): 345-350.

[36]

Sinninghe Damsté J S, Kock-Van Dalen A C, de Leeuw J W, et al. 1988. Identification of homologous series of alkylated thiophenes, thiolanes, thianes and benzothiophenes present in pyrolysates of sulphur-rich kerogens[J]. Journal of Chromatography A, 435: 435-452.

[37]

Stasiuk L D. 1991. Organic petrology and petroleum formation in Paleozoic rocks of northern Williston Basin, Canada[D]. Regina: The University of Regina.

[38]

Stasiuk L D, Osadetz K G, Goodarzi F, et al. 1991. Organic micro-facies and basinal tectonic control on source rock accumulation; a microscopic approach with examples from an intracratonic and extensional basin[J]. International Journal of Coal Geology, 19(1/2/3/4): 457-481.

[39]

Stasiuk L D, Kybett B D, Bend S L. 1993. Reflected light microscopy and micro-FTIR of Upper Ordovician Gloeocapsomorpha prisca alginite in relation to paleoenvironment and petroleum generation, Saskatchewan, Canada[J]. Organic Geochemistry, 20(6): 707-719.

[40]

Umamaheswaran R, Dutta S, Kumar S. 2021. Elucidation of the macromolecular composition of fossil biopolymers using Py-GC×GC-TOFMS[J]. Organic Geochemistry, 151: 104139.

[41]

Zhang Z R, Volkman J K. 2017. Algaenan structure in the microalga Nannochloropsis oculata characterized from stepwise pyrolysis[J]. Organic Geochemistry, 104: 1-7.

[42]

Zhang Z R, Volkman J K, Lu H, et al. 2017. Sources of organic matter in the Eocene Maoming oil shale in SE China as shown by stepwise pyrolysis of asphaltene[J]. Organic Geochemistry, 112: 119-126.

[43]

Zhang Z R, Volkman J K, Xie X M, et al. 2016. Stepwise pyrolysis of the kerogen from the Huadian oil shale, NE China: Algaenan-derived hydrocarbons and mid-chain ketones[J]. Organic Geochemistry, 91: 89-99.

[1]	纪明候.1997.海藻化学[M]. 北京：科学出版社：1-777. Ji Minghou. 1997. Seaweed chemistry[M]. Beijing: Science Press: 1-777.
[2]	梁狄刚，张水昌，张宝民，等. 2000. 从塔里木盆地看中国海相生油问题[J]. 地学前缘，7（4）：534-547. Liang Digang, Zhang Shuichang, Zhang Baomin, et al. 2000. Understanding on marine oil generation in China based on Tarim Basin[J]. Earth Science Frontiers, (4): 534-547.
[3]	刘德汉，肖贤明，贾蓉芬，等. 2000. 碳酸盐岩生烃运移的激光—荧光和有机包裹体研究[J]. 海相油气地质，5（1/2）：62-68. Liu Dehan, Xiao Xianming, Jia Rongfen, et al. 2000. Carbonate hydrocarbon migration of laser-the study of fluorescence and organic in clusions[J]. Marine Origin Petroleum Geology, 5(1/2): 62-68.
[4]	孙永革，茅晟懿，王飞宇，等. 2014. 塔里木盆地奥陶纪地层中Kukersite型生油岩的发现及其石油地质意义[J]. 科学通报，59（1）：72-79. Sun Yongge, Mao Shengyi, Wang Feiyu, et al. 2014. Identification of the Kukersite-type source rocks in the Ordovician stratigraphy from the Tarim Basin, NW China[J]. Chinese Science Bulletin, 59(1): 72-79.
[5]	Bertheas O, Metzger P, Largeau C. 1999. A high molecular weight complex lipid, aliphatic polyaldehyde tetraterpenediol polyacetal from Botryococcus braunii (L race)[J]. Phytochemistry, 50(1): 85-96.
[6]	Blokker P, van Bergen P, Pancost R, et al. 2001. The chemical structure of Gloeocapsomorpha prisca microfossils: Implications for their origin[J]. Geochimica et Cosmochimica Acta, 65(6): 885-900.
[7]	da Silva T F, Mendonça Filho J G, da Silva M C, et al. 2016. Botryococcus braunii versus Gloecapsomorpha prisca: Chemical composition correlation using laser micropyrolysis-gas chromatography/mass spectrometer (LmPy-GCMSMS)[J]. International Journal of Coal Geology, 168: 71-79.
[8]	de Leeuw J W, Largeau C. 1993. A review of macromolecular organic compounds that comprise living organisms and their role in Kerogen, coal, and petroleum formation[M]//Engel M H, Macko S A. Organic geochemistry: Principles and applications. Boston, MA: Springer US: 23-72.
[9]	del Río J C, Gutiérrez A, Rodríguez I M, et al. 2007. Composition of non-woody plant lignins and cinnamic acids by Py-GC/MS, Py/TMAH and FT-IR[J]. Journal of Analytical and Applied Pyrolysis, 79(1/2): 39-46.
[10]	Delahais V, Metzger P. 1997. Four polymethylsqualene epoxides and one acyclic tetraterpene epoxide from Botryococcus braunii [J]. Phytochemistry, 44(4): 671-678.
[11]	Derenne S, Largeau C, Casadevall E, et al. 1990. Characterization of Estonian Kukersite by spectroscopy and pyrolysis: Evidence for abundant alkyl phenolic moieties in an Ordovician, marine, type II/I kerogen[J]. Organic Geochemistry, 16(4/5/6): 873-888.
[12]	Derenne S, Largeau C, Hetényi M, et al. 1997. Chemical structure of the organic matter in a Pliocene maar-type shale: Implicated Botryococcus race strains and formation pathways[J]. Geochimica et Cosmochimica Acta, 61(9): 1879-1889.
[13]	Derenne S, Largeau C, Landais P, et al. 1994. Spectroscopic features of Gloeocapsomorpha prisca colonies and of interstitial matrix in kukersite as revealed by transmission micro-FT-i.r.: Location of phenolic moieties[J]. Fuel, 73(4): 626-628.
[14]	Derenne S, Metzger P, Largeau C, et al. 1992. Similar morphological and chemical variations of Gloeocapsomorpha prisca in Ordovician sediments and cultured Botryococcus braunii as a response to changes in salinity[J]. Organic Geochemistry, 19(4/5/6): 299-313.
[15]	Dillon J G, Castenholz R W. 1999. Scytonemin, a cyanobacterial sheath pigment, protects against UVC radiation: Implications for early photosynthetic life[J]. Journal of Phycology, 35(4): 673-681.
[16]	Douglas A G, Damsté J S S, Fowler M G, et al. 1991. Unique distributions of hydrocarbons and sulphur compounds released by flash pyrolysis from the fossilised alga Gloeocapsomorpha prisca, a major constituent in one of four Ordovician kerogens[J]. Geochimica et Cosmochimica Acta, 55(1): 275-291.
[17]	Foster C B, Reed J D, Wicander R. 1989. Gloeocapsomorpha prisca ZALESSKY, 1917: A new study: Part I: Taxonomy, geochemistry, and paleoecology[J]. Geobios, 22(6): 735-759.
[18]	Fowler M G. 1992. The influence of Gloeocapsomorpha prisca on the organic geochemistry of oils and organic-rich rocks of Late Ordovician age from Canada[M]//Schidlowski M, Golubic S, Kimberley M M, et al. Early organic evolution: Implications for mineral and energy resources. Berlin, Heidelberg: Springer: 336-356.
[19]	Fowler M G, Douglas A G. 1984. Distribution and structure of hydrocarbons in four organic-rich Ordovician rocks[J]. Organic Geochemistry, 6: 105-114.
[20]	Fowler M G, Stasiuk L D, Hearn M, et al. 2004. Evidence for Gloeocapsomorpha prisca in Late Devonian source rocks from southern Alberta, Canada[J]. Organic Geochemistry, 35(4): 425-441.
[21]	Grice K, Schouten S, Peters K E, et al. 1998. Molecular isotopic characterisation of hydrocarbon biomarkers in Palaeocene-Eocene evaporitic, lacustrine source rocks from the Jianghan Basin, China[J]. Organic Geochemistry, 29(5/6/7): 1745-1764.
[22]	Hoffmann C F, Foster C B, Powell T G, et al. 1987. Hydrocarbon biomarkers from Ordovician sediments and the fossil alga Gloeocapsomorpha prisca Zalessky 1917[J]. Geochimica et Cosmochimica Acta, 51(10): 2681-2697.
[23]	Huang Y R, Han X X, Jiang X M. 2014. Comparison of fast pyrolysis characteristics of Huadian oil shales from different mines using Curie-point pyrolysis-GC/MS[J]. Fuel Processing Technology, 128: 456-460.
[24]	Johnson L M, Rezaee R, Smith G C, et al. 2020. Kinetics of hydro-carbon generation from the marine Ordovician Goldwyer Formation, Canning Basin, western Australia[J]. International Journal of Coal Geology, 232: 103623.
[25]	Larter S R, Horsfield B. 1993. Determination of structural components of kerogens by the use of analytical pyrolysis methods [M]//Engel M H, Macko S A. Organic geochemistry: Principles and applications. Boston, MA: Springer US: 271-287.
[26]	Li T, Su J, Wang C, et al. 2022. Advances in the development and application of analytical pyrolysis in biomass research: A review[J]. Energy Conversion and Management, 271: 116302.
[27]	Lille Ü, Heinmaa I, Pehk T. 2003. Molecular model of Estonian kukersite kerogen evaluated by ¹³C MAS NMR spectra[J]. Fuel, 82(7): 799-804.
[28]	Metzger P, Casadevall E. 1992. Ether lipids from Botryococcus braunii and their biosynthesis[J]. Phytochemistry, 31(7): 2341-2349.
[29]	Metzger P, Largeau C. 1994. A new type of ether lipid comprising phenolic moieties in Botryococcus braunii. Chemical structure and abundance, and geochemical implications[J]. Organic Geochemistry, 22(3/4/5): 801-814.
[30]	Metzger P, Pouet Y, Bischoff R, et al. 1993. An aliphatic polyaldehyde from Botryococcus braunii (A race)[J]. Phytochemistry, 32(4): 875-883.
[31]	Nip M, de Leeuw J W, Crelling J C. 1992. Chemical structure of bituminous coal and its constituting maceral fractions as revealed by flash pyrolysis[J]. Energy & Fuels, 6(2): 125-136.
[32]	Reed J D, Illich H A, Horsfield B. 1986. Biochemical evolutionary significance of Ordovician oils and their sources[J]. Organic Geochemistry, 10(1/2/3): 347-358.
[33]	Riboulleau A, Derenne S, Largeau C, et al. 2001. Origin of contrasting features and preservation pathways in kerogens from the Kashpir oil shales (Upper Jurassic, Russian Platform)[J]. Organic Geochemistry, 32(5): 647-665.
[34]	Saiz-jimenez C, Boon J J, Hedges J I, et al. 1987. Chemical characterization of recent and buried woods by analytical pyrolysis: Comparison of pyrolysis data with ¹³C NMR and wet chemical data[J]. Journal of Analytical and Applied Pyrolysis, 11: 437-450.
[35]	Senftle J T, Larter S R, Bromley B W, et al. 1986. Quantitative chemical characterization of vitrinite concentrates using pyrolysis-gas chromatography. Rank variation of pyrolysis products[J]. Organic Geochemistry, 9(6): 345-350.
[36]	Sinninghe Damsté J S, Kock-Van Dalen A C, de Leeuw J W, et al. 1988. Identification of homologous series of alkylated thiophenes, thiolanes, thianes and benzothiophenes present in pyrolysates of sulphur-rich kerogens[J]. Journal of Chromatography A, 435: 435-452.
[37]	Stasiuk L D. 1991. Organic petrology and petroleum formation in Paleozoic rocks of northern Williston Basin, Canada[D]. Regina: The University of Regina.
[38]	Stasiuk L D, Osadetz K G, Goodarzi F, et al. 1991. Organic micro-facies and basinal tectonic control on source rock accumulation; a microscopic approach with examples from an intracratonic and extensional basin[J]. International Journal of Coal Geology, 19(1/2/3/4): 457-481.
[39]	Stasiuk L D, Kybett B D, Bend S L. 1993. Reflected light microscopy and micro-FTIR of Upper Ordovician Gloeocapsomorpha prisca alginite in relation to paleoenvironment and petroleum generation, Saskatchewan, Canada[J]. Organic Geochemistry, 20(6): 707-719.
[40]	Umamaheswaran R, Dutta S, Kumar S. 2021. Elucidation of the macromolecular composition of fossil biopolymers using Py-GC×GC-TOFMS[J]. Organic Geochemistry, 151: 104139.
[41]	Zhang Z R, Volkman J K. 2017. Algaenan structure in the microalga Nannochloropsis oculata characterized from stepwise pyrolysis[J]. Organic Geochemistry, 104: 1-7.
[42]	Zhang Z R, Volkman J K, Lu H, et al. 2017. Sources of organic matter in the Eocene Maoming oil shale in SE China as shown by stepwise pyrolysis of asphaltene[J]. Organic Geochemistry, 112: 119-126.
[43]	Zhang Z R, Volkman J K, Xie X M, et al. 2016. Stepwise pyrolysis of the kerogen from the Huadian oil shale, NE China: Algaenan-derived hydrocarbons and mid-chain ketones[J]. Organic Geochemistry, 91: 89-99.